Enhanced thermoelectric property by the construction of a nanocomposite 3D interconnected architecture consisting of graphene nanolayers sandwiched by polypyrrole nanowires

被引：110

作者：

Zhang, Zhuang ^{[1
]}

Chen, Guangming ^{[1
]}

Wang, Hanfu ^{[2
]}

Zhai, Wentao ^{[3
]}

机构：

[1] Chinese Acad Sci, Inst Chem, BNLMS, Beijing 100190, Peoples R China

[2] Natl Ctr Nanosci & Technol China, Beijing 100190, Peoples R China

[3] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Ningbo Key Lab Polymer Mat, Ningbo 315221, Zhejiang, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY C | 2015年 / 3卷 / 08期

基金：

中国国家自然科学基金;

关键词：

CONDUCTING POLYMER NANOSTRUCTURES; THERMAL-STABILITY; PERFORMANCE; COMPOSITES; NANOGENERATORS; NANOMATERIALS; NANOTUBES; OXIDE;

D O I：

10.1039/c4tc02471k

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A new strategy, i.e. interfacial adsorption-soft template polymerization, is developed to enhance polymer thermoelectric property. The obtained nanocomposite 3D interconnected architecture consisting of reduced graphene oxide (rGO) nanolayers sandwiched by polypyrrole (PPy) nanowires is directly confirmed by scanning and transmission electron microscopies. Moreover, the nanocomposites reveal significantly enhanced thermoelectric performance. At rGO : PPy ratio of 50 wt%, the nanocomposite power factor reaches 476.1 times that of pure PPy nanowires. Our results suggest that a greatly enhanced thermoelectric property for polymer nanocomposites can be achieved by a complex morphology design.

引用

页码：1649 / 1654

页数：6

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