Synthesis of Im3[Mo3(μ3-S)(μ-S2)3Br6]Br (Im=1-ethyl-3-methylimidazolium) in Ionic Liquid: A New Way of Breaking Up Chalcogenide Cluster Coordination Polymers

被引：2
作者：
Sokolov, M. N. [1 ,2 ]
Rogachev, A. V. [1 ]
Virovets, A. V. [1 ]
Piryazev, D. A. [1 ]
Fedin, V. P. [1 ,2 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
来源：
JOURNAL OF CLUSTER SCIENCE | 2015年 / 26卷 / 01期
关键词：
Molybdenum; Chalcogenide clusters; Coordination polymers; Ionic liquid; X-ray structure; CHARGE-TRANSFER SALTS; CRYSTAL-STRUCTURE; COMPLEXES; MO; MO3S7; DITHIOLATE; OXALATE; ROUTE; BR; CL;
D O I：
10.1007/s10876-014-0739-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of 1D cluster coordination polymer Mo3S7Br4 with an ionic liquid composed of 1-ethyl-3-methylimidazolium bromide (ImBr) and AlBr3 in 2:1 molar ratio affords Im(3)[Mo-3(mu(3)-S)(mu-S-2)(3)Br-6]Br (1) in high yield. X-ray structure of 1 center dot CH (3) CN is reported.
引用
收藏
页码：33 / 40
页数：8
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