Preparation and Characterization of Nanocrystalline Hard Chromium Coatings Using Eco-Friendly Trivalent Chromium Bath

被引:8
作者
Protsenko, V. S. [1 ]
Gordiienko, V. O. [1 ]
Danilov, F. I. [1 ]
Kwon, S. C. [2 ]
机构
[1] Ukrainian State Univ Chem Technol, Dept Phys Chem, UA-49005 Dnepropetrovsk, Ukraine
[2] Korea Inst Machinery & Mat, Surface Engn Dept, Chang Won 641010, Gyeongnam, South Korea
关键词
Hard chromium electrodeposition; Trivalent chromium bath; Nanocrystalline; ELECTRODEPOSITION; ELECTROLYTES; KINETICS;
D O I
10.1155/2011/253203
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new aqueous sulfate trivalent chromium bath is described. The chromium bath contains formic acid and carbamide as complexing agents. Chromium was deposited at a temperature of 30 divided by 40 degrees C and a cathode current density of 10 divided by 25 A dm(-2). The bath allows obtaining thick (up to several hundred micrometers) hard chromium coatings with nanocrystalline structure. The electrodeposition rate reaches 0.8 divided by 0.9 mu m min(-1).
引用
收藏
页码:1925 / 1929
页数:5
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