Reactivity of tri(2-furyl)phosphine (PFu3) with [Mn2(CO)10-n(NCMe)n] (n=0-2): X-ray Structure of mer-[Mn(CO)3(η1-C4H3O)(PFu3)2]

被引：12

作者：

Karmaker, Santana ^{[1
]}

Ghosh, Shishir ^{[1
]}

Kabir, Shariff E. ^{[1
]}

Haworth, Daniel T. ^{[2
]}

Lindeman, Sergey V. ^{[2
]}

机构：

[1] Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh

[2] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA

来源：

INORGANICA CHIMICA ACTA | 2012年 / 382卷

关键词：

Manganese; Tri(2-furyl)phosphine; Carbonyl; X-ray structure; CARBONYL-COMPLEXES; COUPLING REACTIONS; BOND-CLEAVAGE; ARYL HALIDES; SUBSTITUTION; LIGAND; PHOSPHORUS; CHEMISTRY; MANGANESE; RHENIUM;

D O I：

10.1016/j.ica.2011.11.053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of tri(2-furyl)phosphine (PFu(3)) with [Mn-2(CO)(10) (n)(NCMe)(n)] (n = 1, 2) at room temperature furnished the substituted complexes [Mn-2(CO)(10) (n)(PFu(3))(n)] (1-2). Direct reaction between Mn-2(CO)(10) and PFu(3) in refluxing toluene also afforded 2 together with mer-[Mn(CO)(3)(eta(1)-C4H3O)(PFu(3))(2)] (3) resulting from phosphorus-carbon bond cleavage of the phosphine. All three new complexes have been characterized by spectroscopic data together with single crystal X-ray diffraction studies for 3. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：199 / 202

页数：4

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