Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks

被引：147
作者：
Rossini, Aaron J. [1 ]
Zagdoun, Alexandre [1 ]
Lelli, Moreno [1 ]
Canivet, Jerome [2 ]
Aguado, Sonia [2 ]
Ouari, Olivier [4 ]
Tordo, Paul [4 ]
Rosay, Melanie [5 ]
Maas, Werner E. [5 ]
Coperet, Christophe [3 ]
Farrusseng, David [2 ]
Emsley, Lyndon [1 ]
Lesage, Anne [1 ]
机构：
[1] Univ Lyon, CNRS ENS Lyon UCB Lyon 1, Ctr RMN Tres Hauts Champs, F-69100 Villeurbanne, France
[2] Univ Lyon, CNRS, IRCELYON, F-69626 Villeurbanne, France
[3] Swiss Fed Inst Technol, Dept Chem, Inorgan Chem Lab, CH-8093 Zurich, Switzerland
[4] Fac St Jerome Case 521, SREP LCP UMR 6264, F-13013 Marseille, France
[5] Bruker BioSpin Corp, Billerica, MA 01821 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 01期
关键词：
dynamic nuclear polarization; hyperpolarization; metal-organic frameworks; solid-state NMR spectroscopy; POROUS COORDINATION POLYMERS; POSTSYNTHETIC MODIFICATION; RETICULAR SYNTHESIS; BUILDING-BLOCKS; TOPOLOGY; CHEMISTRY; DESIGN; MIL-68;
D O I：
10.1002/anie.201106030
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A matter of minutes: Dynamic nuclear polarization (DNP) is applied to enhance the signal of solid-state NMR spectra of metal-organic framework (MOF) materials. The signal enhancement enables the acquisition of high-quality 1D 13C solid-state NMR spectra, 2D 1H- 13C dipolar HETCOR and 1D 15N solid-state NMR spectra with natural isotopic abundance in experiment times on the order of minutes. MW=microwaves. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：123 / 127
页数：5
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