Dynamic Nuclear Polarization Enhanced Solid-State NMR Spectroscopy of Functionalized Metal-Organic Frameworks

被引：147

作者：

Rossini, Aaron J. ^{[1
]}

Zagdoun, Alexandre ^{[1
]}

Lelli, Moreno ^{[1
]}

Canivet, Jerome ^{[2
]}

Aguado, Sonia ^{[2
]}

Ouari, Olivier ^{[4
]}

Tordo, Paul ^{[4
]}

Rosay, Melanie ^{[5
]}

Maas, Werner E. ^{[5
]}

Coperet, Christophe ^{[3
]}

Farrusseng, David ^{[2
]}

Emsley, Lyndon ^{[1
]}

Lesage, Anne ^{[1
]}

机构：

[1] Univ Lyon, CNRS ENS Lyon UCB Lyon 1, Ctr RMN Tres Hauts Champs, F-69100 Villeurbanne, France

[2] Univ Lyon, CNRS, IRCELYON, F-69626 Villeurbanne, France

[3] Swiss Fed Inst Technol, Dept Chem, Inorgan Chem Lab, CH-8093 Zurich, Switzerland

[4] Fac St Jerome Case 521, SREP LCP UMR 6264, F-13013 Marseille, France

[5] Bruker BioSpin Corp, Billerica, MA 01821 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 01期

关键词：

dynamic nuclear polarization; hyperpolarization; metal-organic frameworks; solid-state NMR spectroscopy; POROUS COORDINATION POLYMERS; POSTSYNTHETIC MODIFICATION; RETICULAR SYNTHESIS; BUILDING-BLOCKS; TOPOLOGY; CHEMISTRY; DESIGN; MIL-68;

D O I：

10.1002/anie.201106030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A matter of minutes: Dynamic nuclear polarization (DNP) is applied to enhance the signal of solid-state NMR spectra of metal-organic framework (MOF) materials. The signal enhancement enables the acquisition of high-quality 1D 13C solid-state NMR spectra, 2D 1H- 13C dipolar HETCOR and 1D 15N solid-state NMR spectra with natural isotopic abundance in experiment times on the order of minutes. MW=microwaves. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：123 / 127

页数：5

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