A Study of Films Based on Acrylic Copolymers: Mesoscopic Simulation

被引:3
作者
Buglakov, A., I [1 ,2 ]
Ivanov, V. A. [1 ,3 ]
Komarov, P., V [2 ,4 ]
Zherenkova, L., V [4 ]
Chiu, Yu-T [5 ]
机构
[1] Moscow MV Lomonosov State Univ, Fac Phys, Moscow 119991, Russia
[2] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
[3] Univ Halle, Inst Phys, D-06099 Halle, Germany
[4] Tver State Univ, Tver 170100, Russia
[5] Ind Technol Res Inst, Hsinchu 31040, Taiwan
基金
俄罗斯基础研究基金会;
关键词
DYNAMICS; ADHESION;
D O I
10.1134/S0965545X20030049
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Aqueous solutions of an acrylic copolymer and a low-molecular-weight anionic surfactant are studied using mesoscopic simulation by dissipative particle dynamics. The possibility of formation of a homogeneous film from the acrylic copolymer, where a domain structure is absent and a surfactant is separated from the polymer phase, is studied. A mesoscopic model taking into account the main structural features of the acrylic copolymer chain and the surfactant is proposed. It was shown that a change in the parameters of electrostatic interaction influences the fineness of the systems under study, but does not change the morphology of forming films. Conditions for the preparation of a film with homogeneous morphology are stated.
引用
收藏
页码:307 / 319
页数:13
相关论文
共 41 条
[1]  
[Anonymous], 1987, COMPUTER SIMULATIONO
[2]   Surfactant Distribution in Waterborne Acrylic Films. 1. Bulk Investigation [J].
Arnold, Celine ;
Thalmann, Fabrice ;
Marques, Carlos ;
Marie, Pascal ;
Holl, Yves .
JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (28) :9135-9147
[3]  
ASKADSKII AA, 2001, COMPUTATIONAL MAT SC
[4]   Theoretical Study of Twin Polymerization - From Chemical Reactivity to Structure Formation [J].
Auer, Alexander A. ;
Richter, Antje ;
Berezkin, Anatoly V. ;
Guseva, Daria V. ;
Spange, Stefan .
MACROMOLECULAR THEORY AND SIMULATIONS, 2012, 21 (09) :615-628
[5]   Hildebrand and Hansen solubility parameters from molecular dynamics with applications to electronic nose polymer sensors [J].
Belmares, M ;
Blanco, M ;
Goddard, WA ;
Ross, RB ;
Caldwell, G ;
Chou, SH ;
Pham, J ;
Olofson, PM ;
Thomas, C .
JOURNAL OF COMPUTATIONAL CHEMISTRY, 2004, 25 (15) :1814-1826
[6]   Vertical Domain Orientation in Cylinder-Forming Diblock Copolymer Films upon Solvent Vapor Annealing [J].
Berezkin, Anatoly V. ;
Papadakis, Christine M. ;
Potemkin, Igor I. .
MACROMOLECULES, 2016, 49 (01) :415-424
[7]  
Brazel C. S., 2012, FUNDAMENTAL PRINCIPL, V3rd, ppp456
[8]   Effect of surfactant systems on the water sensitivity of latex films [J].
Butler, LN ;
Fellows, CM ;
Gilbert, RG .
JOURNAL OF APPLIED POLYMER SCIENCE, 2004, 92 (03) :1813-1823
[9]   STATISTICAL-MECHANICS OF DISSIPATIVE PARTICLE DYNAMICS [J].
ESPANOL, P ;
WARREN, P .
EUROPHYSICS LETTERS, 1995, 30 (04) :191-196
[10]   HYDRODYNAMICS FROM DISSIPATIVE PARTICLE DYNAMICS [J].
ESPANOL, P .
PHYSICAL REVIEW E, 1995, 52 (02) :1734-1742