Double-core-hole spectroscopy for chemical analysis with an intense X-ray femtosecond laser

被引：155

作者：

Berrah, Nora ^{[1
]}

Fang, Li ^{[1
]}

Murphy, Brendan ^{[1
]}

Osipov, Timur ^{[1
]}

Ueda, Kiyoshi ^{[2
]}

Kukk, Edwin ^{[3
]}

Feifel, Raimund ^{[4
]}

van der Meulen, Peter ^{[5
]}

Salen, Peter ^{[5
]}

Schmidt, Henning T. ^{[5
]}

Thomas, Richard D. ^{[5
]}

Larsson, Mats ^{[5
]}

Richter, Robert ^{[6
]}

Prince, Kevin C. ^{[6
]}

Bozek, John D. ^{[7
]}

Bostedt, Christoph ^{[7
]}

Wada, Shin-ichi ^{[7
,8
]}

Piancastelli, Maria N. ^{[4
]}

Tashiro, Motomichi ^{[9
]}

Ehara, Masahiro ^{[9
]}

机构：

[1] Western Michigan Univ, Dept Phys, Kalamazoo, MI 49008 USA

[2] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Sendai, Miyagi 9808577, Japan

[3] Univ Turku, Dept Phys & Astron, FI-20014 Turku, Finland

[4] Uppsala Univ, Dept Phys & Astron, SE-751 Uppsala, Sweden

[5] Stockholm Univ, Dept Phys, SE-10691 Stockholm, Sweden

[6] Sincrotrone Trieste, Elettra & Fermi Elettra, I-34149 Trieste, Italy

[7] Stanford Linear Accelerator Ctr, Linac Coherent Light Source, Menlo Pk, CA 94025 USA

[8] Hiroshima Univ, Dept Phys Sci, Higashihiroshima 7398526, Japan

[9] Natl Inst Nat Sci, Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | 2011年 / 108卷 / 41期

基金：

日本科学技术振兴机构; 瑞典研究理事会;

关键词：

multi-photon ionization; ultrafast; two-photon spectroscopy; ATOMS;

D O I：

10.1073/pnas.1111380108

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Theory predicts that double-core-hole (DCH) spectroscopy can provide a new powerful means of differentiating between similar chemical systems with a sensitivity not hitherto possible. Although DCH ionization on a single site in molecules was recently measured with double-and single-photon absorption, double-core holes with single vacancies on two different sites, allowing unambiguous chemical analysis, have remained elusive. Here we report that direct observation of double-core holes with single vacancies on two different sites produced via sequential two-photon absorption, using short, intense X-ray pulses from the Linac Coherent Light Source free-electron laser and compare it with theoretical modeling. The observation of DCH states, which exhibit a unique signature, and agreement with theory proves the feasibility of the method. Our findings exploit the ultrashort pulse duration of the free-electron laser to eject two core electrons on a time scale comparable to that of Auger decay and demonstrate possible future X-ray control of physical inner-shell processes.

引用

页码：16912 / 16915

页数：4

共 20 条

[1] Operation of a free-electron laser from the extreme ultraviolet to the water window [J].

Ackermann, W. ;

Asova, G. ;

Ayvazyan, V. ;

Azima, A. ;

Baboi, N. ;

Baehr, J. ;

Balandin, V. ;

Beutner, B. ;

Brandt, A. ;

Bolzmann, A. ;

Brinkmann, R. ;

Brovko, O. I. ;

Castellano, M. ;

Castro, P. ;

Catani, L. ;

Chiadroni, E. ;

Choroba, S. ;

Cianchi, A. ;

Costello, J. T. ;

Cubaynes, D. ;

Dardis, J. ;

Decking, W. ;

Delsim-Hashemi, H. ;

Delserieys, A. ;

Di Pirro, G. ;

Dohlus, M. ;

Duesterer, S. ;

Eckhardt, A. ;

Edwards, H. T. ;

Faatz, B. ;

Feldhaus, J. ;

Floettmann, K. ;

Frisch, J. ;

Froehlich, L. ;

Garvey, T. ;

Gensch, U. ;

Gerth, Ch. ;

Goerler, M. ;

Golubeva, N. ;

Grabosch, H.-J. ;

Grecki, M. ;

Grimm, O. ;

Hacker, K. ;

Hahn, U. ;

Han, J. H. ;

Honkavaara, K. ;

Hott, T. ;

Huening, M. ;

Ivanisenko, Y. ;

Jaeschke, E. .

NATURE PHOTONICS, 2007, 1 (06) :336-342

[2] Non-linear processes in the interaction of atoms and molecules with intense EUV and X-ray fields from SASE free electron lasers (FELs) [J].

Berrah, N. ;

Bozek, J. ;

Costello, J. T. ;

Duesterer, S. ;

Fang, L. ;

Feldhaus, J. ;

Fukuzawa, H. ;

Hoener, M. ;

Jiang, Y. H. ;

Johnsson, P. ;

Kennedy, E. T. ;

Meyer, M. ;

Moshammer, R. ;

Radcliffe, P. ;

Richter, M. ;

Rouzee, A. ;

Rudenko, A. ;

Sorokin, A. A. ;

Tiedtke, K. ;

Ueda, K. ;

Ullrich, J. ;

Vrakking, M. J. J. .

JOURNAL OF MODERN OPTICS, 2010, 57 (12) :1015-1040

[3]

Björneholm O, 2001, J CHEM PHYS, V115, P4139, DOI 10.1063/1.1380690

[4] AMO instrumentation for the LCLS X-ray FEL [J].

Bozek, J. D. .

EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS, 2009, 169 :129-132

[5] ON DOUBLE VACANCIES IN THE CORE [J].

CEDERBAUM, LS ;

TARANTELLI, F ;

SGAMELLOTTI, A ;

SCHIRMER, J .

JOURNAL OF CHEMICAL PHYSICS, 1986, 85 (11) :6513-6523

[6] Comparing different approaches to characterization of focused X-ray laser beams [J].

Chalupsky, J. ;

Bohacek, P. ;

Hajkova, V. ;

Hau-Riege, S. P. ;

Heimann, P. A. ;

Juha, L. ;

Krzywinski, J. ;

Messerschmidt, M. ;

Moeller, S. P. ;

Nagler, B. ;

Rowen, M. ;

Schlotter, W. F. ;

Swiggers, M. L. ;

Turner, J. J. .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT, 2011, 631 (01) :130-133

[7] Femtosecond X-ray protein nanocrystallography [J].

Chapman, Henry N. ;

Fromme, Petra ;

Barty, Anton ;

White, Thomas A. ;

Kirian, Richard A. ;

Aquila, Andrew ;

Hunter, Mark S. ;

Schulz, Joachim ;

DePonte, Daniel P. ;

Weierstall, Uwe ;

Doak, R. Bruce ;

Maia, Filipe R. N. C. ;

Martin, Andrew V. ;

Schlichting, Ilme ;

Lomb, Lukas ;

Coppola, Nicola ;

Shoeman, Robert L. ;

Epp, Sascha W. ;

Hartmann, Robert ;

Rolles, Daniel ;

Rudenko, Artem ;

Foucar, Lutz ;

Kimmel, Nils ;

Weidenspointner, Georg ;

Holl, Peter ;

Liang, Mengning ;

Barthelmess, Miriam ;

Caleman, Carl ;

Boutet, Sebastien ;

Bogan, Michael J. ;

Krzywinski, Jacek ;

Bostedt, Christoph ;

Bajt, Sasa ;

Gumprecht, Lars ;

Rudek, Benedikt ;

Erk, Benjamin ;

Schmidt, Carlo ;

Hoemke, Andre ;

Reich, Christian ;

Pietschner, Daniel ;

Strueder, Lothar ;

Hauser, Guenter ;

Gorke, Hubert ;

Ullrich, Joachim ;

Herrmann, Sven ;

Schaller, Gerhard ;

Schopper, Florian ;

Soltau, Heike ;

Kuehnel, Kai-Uwe ;

Messerschmidt, Marc .

NATURE, 2011, 470 (7332) :73-U81

[8] Auger Electron Angular Distribution of Double Core-Hole States in the Molecular Reference Frame [J].

Cryan, James P. ;

Glownia, J. M. ;

Andreasson, J. ;

Belkacem, A. ;

Berrah, N. ;

Blaga, C. I. ;

Bostedt, C. ;

Bozek, J. ;

Buth, C. ;

DiMauro, L. F. ;

Fang, L. ;

Gessner, O. ;

Guehr, M. ;

Hajdu, J. ;

Hertlein, M. P. ;

Hoener, M. ;

Kornilov, O. ;

Marangos, J. P. ;

March, A. M. ;

McFarland, B. K. ;

Merdji, H. ;

Petrovic, V. S. ;

Raman, C. ;

Ray, D. ;

Reis, D. ;

Tarantelli, F. ;

Trigo, M. ;

White, J. L. ;

White, W. ;

Young, L. ;

Bucksbaum, P. H. ;

Coffee, R. N. .

PHYSICAL REVIEW LETTERS, 2010, 105 (08)

[9] Measurements and Simulations of Ultralow Emittance and Ultrashort Electron Beams in the Linac Coherent Light Source [J].

Ding, Y. ;

Brachmann, A. ;

Decker, F. -J. ;

Dowell, D. ;

Emma, P. ;

Frisch, J. ;

Gilevich, S. ;

Hays, G. ;

Hering, Ph. ;

Huang, Z. ;

Iverson, R. ;

Loos, H. ;

Miahnahri, A. ;

Nuhn, H. -D. ;

Ratner, D. ;

Turner, J. ;

Welch, J. ;

White, W. ;

Wu, J. .

PHYSICAL REVIEW LETTERS, 2009, 102 (25)

[10] Double Core Hole Creation and Subsequent Auger Decay in NH3 and CH4 Molecules [J].

Eland, J. H. D. ;

Tashiro, M. ;

Linusson, P. ;

Ehara, M. ;

Ueda, K. ;

Feifel, R. .

PHYSICAL REVIEW LETTERS, 2010, 105 (21)

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