Synthesis of novel chiral unsymmetrical imidazolinium bromides

被引：6

作者：

Yang, Longguang ^{[1
,2
]}

Sun, Rui ^{[1
,2
]}

Zhang, Lingqiao ^{[1
,2
]}

Li, Yunfei ^{[1
,2
]}

Cao, Changsheng ^{[1
,2
]}

Pang, Guangsheng ^{[3
]}

Shi, Yanhui ^{[1
,2
,4
]}

机构：

[1] Xuzhou Normal Univ, Sch Chem & Chem Engn, Xuzhou 221116, Jiangsu, Peoples R China

[2] Xuzhou Normal Univ, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China

[3] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Coll Chem, Changchun 130012, Jilin, Peoples R China

[4] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2011年 / 10期

关键词：

chiral; imidazolinium; L-phenylalanine; N-heterocyclic carbene; organometallic catalysts; N-HETEROCYCLIC CARBENES; CATALYSTS; LIGANDS;

D O I：

10.3184/174751911X13179972094859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-heterocyclic carbenes have been successfully used as ligands in organometallic catalysis, and also as organocatalysts in different reactions. A series of novel chiral unsymmetrical imidazolinium salts which are precursors of N-heterocylic carbenes were synthesised effectively from the relatively inexpensive amino acid L-phenylalanine in six steps. These chiral unsymmetrical imidazolinium bromides were fully characterised by NMR and elemental analysis, and their specific rotations were obtained.

引用

页码：608 / 610

页数：3

共 50 条

[41] Synthesis and electrochemistry of novel unsymmetrical viologen dendrimers.
Ong, W
Kaifer, A
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U128 - U129
[42] Synthesis and characterization of novel unsymmetrical porphyrin and its complexes
Shi, Yuhua
Tang, Xuexin
Sun, Erjun
Cheng, Xiuli
Wang, Dong
Yu, Shuangjiang
Shi, Tongshun
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2008, 38 (05) : 431 - 438
[43] Novel synthesis of unsymmetrical azines from semicarbazones and aldehydes
Ren, ZJ
Cao, WG
Tong, WQ
Xi, JJ
SYNTHETIC COMMUNICATIONS, 2001, 31 (01) : 125 - 129
[44] A novel method for the synthesis of unsymmetrical sulfides, thioesters and β-thioesters
Tian, FS
Zhu, YM
Zhang, SL
Wang, YL
JOURNAL OF CHEMICAL RESEARCH, 2002, (11) : 582 - 583
[45] Chiral Imidazolinium Salts with TIPS Groups for the Palladium-Catalyzed α-Arylation and as Chiral Solvating Agents
Gilani, Mazhar Amjad
Rais, Eduard
Wilhelm, Rene
SYNLETT, 2015, 26 (11) : 1638 - 1641
[46] Design and synthesis of imidazolinium salts derived from (L)-valine. Investigation of their potential in chiral molecular recognition
Clavier, H
Boulanger, L
Audic, N
Toupet, L
Mauduit, M
Guillemin, JC
CHEMICAL COMMUNICATIONS, 2004, (10) : 1224 - 1225
[47] Novel imidazolinium ionic liquids and organic salts
Chong, Alison L.
Forsyth, Maria
MacFarlane, Douglas R.
ELECTROCHIMICA ACTA, 2015, 159 : 219 - 226
[48] Manganese(III) complexes of novel chiral unsymmetrical BINOL-Salen ligands: Synthesis, characterization, and application in asymmetric epoxidation of olefins
Chen, Longhai
Cheng, Feixiang
Jia, Lei
Wang, Lei
Wei, Jian
Zhang, Jinfeng
Yao, Lihui
Tang, Ning
Wu, Jincai
APPLIED CATALYSIS A-GENERAL, 2012, 415 : 40 - 46
[49] A facile preparation of backbone-substituted, functionalized and chiral imidazolinium salts
Zhang, Jun
Su, Xiaolong
Fu, Jun
Shi, Min
CHEMICAL COMMUNICATIONS, 2011, 47 (46) : 12541 - 12543
[50] Novel imidazolium and imidazolinium salts containing the 9-nickelafluorenyl anion - synthesis, structures and reactivity
Buchalski, Piotr
Pacholski, Roman
Chodkiewicz, Krzysztof
Buchowicz, Wlodzimierz
Suwinska, Kinga
Shkurenko, Aleksander
DALTON TRANSACTIONS, 2015, 44 (16) : 7169 - 7176

← 1 2 3 4 5 →