Superior storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-ion batteries

被引:903
作者
Hu, Yong-Sheng [1 ]
Demir-Cakan, Rezan [2 ]
Titirici, Maria-Magdalena [2 ]
Mueller, Jens-Oliver [3 ]
Schloegl, Robert [3 ]
Antonietti, Markus [2 ]
Maier, Joachim [1 ]
机构
[1] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany
[2] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany
[3] Fritz Haber Inst Max Planck Gesellschaft, D-14195 Berlin, Germany
关键词
anode materials; carbon; lithium-ion batteries; nanoparticles; silicon;
D O I
10.1002/anie.200704287
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Full charge ahead: Hydrothermal carbonization of glucose in the presence of Si nanoparticles yields a Si@SiOx/C nanocomposite that has high reversible lithium-storage capacity, excellent cycling performance, and high rate capability. This material shows promise as an anode material in lithium-ion batteries. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1645 / 1649
页数:5
相关论文
共 49 条
[1]   Nanostructured materials for advanced energy conversion and storage devices [J].
Aricò, AS ;
Bruce, P ;
Scrosati, B ;
Tarascon, JM ;
Van Schalkwijk, W .
NATURE MATERIALS, 2005, 4 (05) :366-377
[2]   TiO2(B) nanowires as an improved anode material for lithium-ion batteries containing LiFePO4 or LiNi0.5Mn1.5O4 cathodes and a polymer electrolyte [J].
Armstrong, Graham ;
Armstrong, A. Robert ;
Bruce, Peter G. ;
Reale, Priscilla ;
Scrosati, Bruno .
ADVANCED MATERIALS, 2006, 18 (19) :2597-+
[3]   On the use of vinylene carbonate (VC) electrolyte solutions for Li-ion as an additive to batteries [J].
Aurbach, D ;
Gamolsky, K ;
Markovsky, B ;
Gofer, Y ;
Schmidt, M ;
Heider, U .
ELECTROCHIMICA ACTA, 2002, 47 (09) :1423-1439
[4]   Amorphous silicon thin films as a high capacity anodes for Li-ion batteries in ionic liquid electrolytes [J].
Baranchugov, V. ;
Markevich, E. ;
Pollak, E. ;
Salitra, G. ;
Aurbach, D. .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (04) :796-800
[5]   Will advanced lithium-alloy anodes have a chance in lithium-ion batteries? [J].
Besenhard, JO ;
Yang, J ;
Winter, M .
JOURNAL OF POWER SOURCES, 1997, 68 (01) :87-90
[6]   Self-assembled vanadium pentoxide (V2O5) hollow microspheres from nanorods and their application in lithium-ion batteries [J].
Cao, AM ;
Hu, JS ;
Liang, HP ;
Wan, LJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (28) :4391-4395
[7]   Enhancing electrochemical performance of silicon film anode by vinylene carbonate electrolyte additive [J].
Chen, Libao ;
Wang, Ke ;
Xie, Xiaohua ;
Xie, Jingying .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (11) :A512-A515
[8]   Novel nano-silicon/polypyrrole composites for lithium storage [J].
Chew, S. Y. ;
Guo, Z. P. ;
Wang, J. Z. ;
Chen, J. ;
Munroe, P. ;
Ng, S. H. ;
Zhao, L. ;
Liu, H. K. .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (05) :941-946
[9]   Photonic crystal structures as a basis for a three-dimensionally interpenetrating electrochemical-cell system [J].
Ergang, Nicholas S. ;
Lytle, Justin C. ;
Lee, Kyu T. ;
Oh, Seung M. ;
Smyrl, William H. ;
Stein, Andreas .
ADVANCED MATERIALS, 2006, 18 (13) :1750-+
[10]  
Gao B, 2001, ADV MATER, V13, P816, DOI 10.1002/1521-4095(200106)13:11<816::AID-ADMA816>3.0.CO