Palladium-catalyzed carbonylation of aryl tosylates and mesylates

被引：174
|
作者：
Munday, Rachel H. [1 ]
Martinelli, Joseph R. [1 ]
Buchwald, Stephen L. [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 09期
关键词：
D O I：
10.1021/ja711449e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A general protocol for the palladium-catalyzed carbonylation of aryl tosylates and mesylates to form esters has been developed using a catalyst system derived from Pd(OAC)2 and the bulky, bidentate dcpp ligand. The system operates under mild conditions: atmospheric CO pressure and temperatures of 80-110 degrees C. A broad substrate scope has been demonstrated allowing carbonylation of electron-rich, electron-poor, and heterocyclic tosylates and mesylates, and the reaction shows wide functional group tolerance.
引用
收藏
页码：2754 / +
页数：3
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