Synthesis, crystal structure and photoluminescent property of a 3D hydrogen-bonded supramolecular compound with large channels

被引：0

作者：

Yue Cheng-Yang ^{[1
]}

Jiang Fei-Long ^{[1
]}

Yuan Da-Qiang ^{[1
]}

Chen Lian ^{[1
]}

Wu Ming-Yan ^{[1
]}

Hong Mao-Chun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2008年 / 27卷 / 04期

关键词：

5-aminodiacetic isophthalic acid; channel; hydrogen bonds; palladium;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound, [Pd(2,2'-bipy)(2)](H(3)adiP)(2 center dot)4H(2)O, was synthesized via the hydrothermal reaction of PdCl2 with 5-aminodiaceti,c isophthalic acid (H(4)adip) in an acetic acid water solution. It was characterized by elemental analysis and infrared spectrum. Crystal data for C44H44N6O20Pd: monoclinic, space group P2(1)/n, a = 11.0674(2), b = 9.9716(2), c = 20.5770(3) A, beta = 92.7300(3)degrees, V = 2268.29(7) angstrom(3), Z = 2, M-r = 1083.25, D-c = 1.586 g/cm(3), F(000) = 1112, mu = 0.499 mm(-1), lambda(MoK alpha) = 0.71073 angstrom, T = 293(2) K, 2 theta(max) = 51.38', GOOF = 1.067, R = 0.0268 and wR = 0.0710 for 3770 reflections with I > 2 sigma(I). X-ray diffraction studies reveal that the title compound has an interesting 3D microporous architecture via hydrogen bonds with the cations located inside the channel.

引用

页码：467 / 470

页数：4

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