Adsorption of anionic surfactant at the electrode-NaClO4 solution interface

被引：12
|
作者：
Gugala-Fekner, Dorota [1 ]
Nieszporek, Jolanta [1 ]
Sienko, Dorota [1 ]
机构：
[1] Marie Curie Sklodowska Univ, Fac Chem, PL-20031 Lublin, Poland
来源：
MONATSHEFTE FUR CHEMIE | 2015年 / 146卷 / 04期
关键词：
Differential capacity; Adsorption isotherms; Anionic surfactant; Electrosorption; Mercury electrode; MERCURY;
D O I：
10.1007/s00706-014-1382-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Adsorption of 1-decanesulfonic acid at the electrode-NaClO4 solution interface was determined by double-layer differential capacity measurements. At potentials less than -1,200 mV, the adsorption of the anionic surfactant on the electrode does not occur. Low concentrations of the anionic surfactant (below cmc) causes slight changes in the zero charge potential, E (z), and the surface tension at this potential, gamma (z). The adsorption of the anionic surfactant was analyzed using the constants obtained from the following isotherms: Frumkin, corrected Flory-Huggins, and virial.
引用
收藏
页码：541 / 545
页数：5
相关论文
共 50 条
  • [1] Adsorption of anionic surfactant at the electrode–NaClO4 solution interface
    Dorota Gugała-Fekner
    Jolanta Nieszporek
    Dorota Sieńko
    Monatshefte für Chemie - Chemical Monthly, 2015, 146 : 541 - 545
  • [2] Adsorption of N-decanoyl-N-methylglucamine at the Interface Electrode-NaClO4 Solution. Comparison of Adsorption Properties of Different Surfactants
    Gugala-Fekner, Dorota
    CROATICA CHEMICA ACTA, 2016, 89 (01) : 25 - 30
  • [3] The Octyltrimethylamonium Bromide Adsorption at the Mercury Electrode / NaClO4 Solution Interface
    Gugala-Fekner, Dorota
    Nieszporek, Jolanta
    Sienko, Dorota
    ACTA CHIMICA SLOVENICA, 2016, 63 (02) : 258 - 262
  • [4] ADSORPTION OF AMPHOLYTIC SURFACTANT AND ANIONIC SURFACTANT AT NITROGEN-SOLUTION INTERFACE FROM MIXED AQUEOUS-SOLUTION
    NAKAMURA, A
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1975, 48 (06) : 1720 - 1724
  • [5] MIXED ADSORPTION OF A NONIONIC AND AN ANIONIC SURFACTANT AT THE CARBON AQUEOUS-SOLUTION INTERFACE
    HEY, MJ
    MACTAGGART, JW
    ROCHESTER, CH
    JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 : 1805 - 1811
  • [6] Adsorption of Model Perfumes at the Air-Solution Interface by Coadsorption with an Anionic Surfactant
    Bradbury, Robert
    Penfold, Jeffrey
    Thomas, Robert K.
    Tucker, Ian M.
    Petkov, Jordan T.
    Jones, Craig
    LANGMUIR, 2013, 29 (10) : 3361 - 3369
  • [7] Titrimetric determination of anionic surfactant content in anionic/nonionic surfactant mixture solution by anionic surfactant selective electrode
    Wang, Junwei
    Du, Zhiping
    Wang, Wanxu
    Xue, Wei
    TURKISH JOURNAL OF CHEMISTRY, 2012, 36 (04) : 545 - 555
  • [8] The Adsorption of Tetramethylthiourea at the Interface Electrode - NaClO4 in the Presence of Sodium 1-decanesulfonate
    Klin, Malgorzata
    Nieszporek, Jolanta
    Sienko, Dorota
    Gugala-Fekner, Dorota
    Saba, Jadwiga
    ACTA CHIMICA SLOVENICA, 2011, 58 (01) : 26 - 32
  • [9] ADSORPTION MECHANISM OF A CATIONIC SURFACTANT ON TEXTILES IN EXCESS ANIONIC SURFACTANT SOLUTION
    YANABA, S
    KANAO, H
    OKUMURA, O
    JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1988, 65 (12) : 1977 - 1981
  • [10] Sequential Adsorption of an Irreversibly Adsorbed Nonionic Surfactant and an Anionic Surfactant at an Oil/Aqueous Interface
    Kirby, Stephanie M.
    Anna, Shelley L.
    Walker, Lynn M.
    LANGMUIR, 2015, 31 (14) : 4063 - 4071
12345