Removal of heavy metals in aquatic environment by graphene oxide composites: a review

被引:82
作者
Zhang, Quan [1 ,2 ]
Hou, Qinxuan [1 ,3 ]
Huang, Guanxing [1 ]
Fan, Qi [4 ]
机构
[1] Chinese Acad Geol Sci, Inst Hydrogeol & Environm Geol, Shijiazhuang, Hebei, Peoples R China
[2] China Univ Geosci, Beijing, Peoples R China
[3] Hebei Key Lab Groundwater Remediat, Shijiazhuang, Hebei, Peoples R China
[4] East China Mineral Explorat & Dev Bur, Nanjing, Peoples R China
关键词
Graphene oxide; Composites; Heavy metals; Adsorption; Aquatic environment; ZERO-VALENT IRON; ELECTROCHEMICALLY ASSISTED COAGULATION; SOLID-PHASE EXTRACTION; WASTE-WATER TREATMENT; AQUEOUS-SOLUTIONS; GRAPHITE OXIDE; HEXAVALENT CHROMIUM; EFFICIENT REMOVAL; ALGINATE BEADS; OXIDE/CHITOSAN COMPOSITE;
D O I
10.1007/s11356-019-06683-w
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
As the most important graphene derivate, graphene oxide (GO) is a high-efficient adsorbent for the removal of heavy metals in aquatic environment due to its abundant oxygen functional groups, enormous specific area, and strong hydrophilia. However, there are some drawbacks, such as easily aggregating and difficult separation, restricting the environmental application of GO. GO is not a suitable adsorbent by itself. Hence, some materials were used to synthesize GO composites, and GO composites are commonly characterized by high adsorption capacity to overcome the above drawbacks. This review discusses five main GO composites-GO-chitosan, GO-alginate, GO-SiO2, NZVI-rGO, and magnetic GO composites-and summarizes the synthesis methods of GO composites and its application for the removal of heavy metals in aquatic environments. The influencing factors, adsorption capacities, and mechanisms related to the removal of heavy metals by GO composites are highlighted. Lastly, the application potentials and challenges of GO composites for aqueous environmental remediation are discussed.
引用
收藏
页码:190 / 209
页数:20
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