Homocoupling of aldimines mediated by zirconocene: synthesis of vicinal diamines and imidazolidines

被引：6

作者：

Soueidan, Mohamad ^{[1
]}

Helion, Florence ^{[1
]}

Namy, Jean-Louis ^{[1
]}

Szymoniak, Jan ^{[2
]}

机构：

[1] Univ Paris 11, ICMMO, Equipe Catalyse Mol, CNRS,UMR 8182, F-91405 Orsay, France

[2] Univ Reims, Inst Chim Mol Reims, CNRS, UMR 6229, F-51687 Reims 2, France

来源：

TETRAHEDRON LETTERS | 2011年 / 52卷 / 12期

关键词：

Lanthanides; Zirconocene; Aldimine coupling; Imidazolidine; REDUCTIVE DIMERIZATION; TETRAHYDROFOLIC ACID; IMINES; CONDENSATION; FORMALDEHYDE; TITANIUM; ROUTE; ORGANOSILANES; CYCLIZATION; COMPLEXES;

D O I：

10.1016/j.tetlet.2011.01.075

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reductive coupling of imines in the presence of the lanthanide-originated zirconocene equivalent allows the synthesis of vicinal diamines or imidazolidines under mild conditions in good yields with high diastereoselectivity. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：1348 / 1350

页数：3

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