Propagation of photosensitive chemical waves on the circular routes

被引:11
作者
Kitahata, H
Yamada, A
Nakata, S
Ichino, T
机构
[1] Nara Univ Educ, Dept Chem, Nara 6308528, Japan
[2] Kyoto Univ, Grad Sch Sci, Dept Phys, Kyoto 6068502, Japan
关键词
D O I
10.1021/jp0507905
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The propagation of chemical waves in the photosensitive Belousov-Zhabotinsky (BZ) reaction was investigated using an excitable field in the shape of a circular ring or figure "8" that was drawn by computer software and then projected on a film soaked with BZ solution using a liquid-crystal projector. For a chemical wave in a circular reaction field, the shape of the chemical wave was investigated depending on the ratio of the inner and outer radii. When two chemical waves were generated on a field shaped like a figure "8" (one chemical wave in each circle) as the initial condition, the location of the collision of the waves either was constant or alternated depending on the degree of overlap of the two circular rings. These experimental results were analyzed on the basis of a geometrical discussion and theoretically reproduced on the basis of a reaction-diffusion system using a modified Oregonator model. These results suggest that the photosensitive BZ reaction may be useful for creating spatio-temporal patterns depending on the geometric arrangement of excitable fields.
引用
收藏
页码:4973 / 4978
页数:6
相关论文
共 31 条
[1]   Chemical diode [J].
Agladze, K ;
Aliev, RR ;
Yamaguchi, T ;
Yoshikawa, K .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (33) :13895-13897
[2]   CRITICAL CONDITIONS OF CHEMICAL WAVE-PROPAGATION IN GEL LAYERS WITH AN IMMOBILIZED CATALYST [J].
ALIEV, RR ;
AGLADZE, KI .
PHYSICA D, 1991, 50 (01) :65-70
[3]   Experimental and model studies of oscillations, photoinduced transitions, and steady states in the Ru(bPY)32+-catalyzed Belousov-Zhabotinsky reaction under different solute compositions [J].
Amemiya, T ;
Yamamoto, T ;
Ohmori, T ;
Yamaguchi, T .
JOURNAL OF PHYSICAL CHEMISTRY A, 2002, 106 (04) :612-620
[4]  
Field RJ., 1985, Oscillations and traveling waves in chemical systems
[5]   T-shaped coincidence detector as a band filter of chemical signal frequency [J].
Gorecka, J ;
Gorecki, J .
PHYSICAL REVIEW E, 2003, 67 (06) :4
[6]   On chemical reactors that can count [J].
Gorecki, J ;
Yoshikawa, K ;
Igarashi, Y .
JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (10) :1664-1669
[7]   Different operations on a single circuit: Field computation on an excitable chemical system [J].
Ichino, T ;
Igarashi, Y ;
Motoike, IN ;
Yoshikawa, K .
JOURNAL OF CHEMICAL PHYSICS, 2003, 118 (18) :8185-8190
[8]  
Iguchi Y, 1998, RRD PURE APPL CHEM, V2, P113
[9]   Reaction mechanism for light sensitivity of the Ru(bpy)(3)(2+)-catalyzed Belousov-Zhabotinsky reaction [J].
Kadar, S ;
Amemiya, T ;
Showalter, K .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (44) :8200-8206
[10]  
Kapral R., 1995, CHEM WAVES PATTERNS