A magnesium-sodium hybrid battery with high operating voltage

被引：58

作者：

Dong, Hui ^{[1
]}

Li, Yifei ^{[1
]}

Liang, Yanliang ^{[1
]}

Li, Guosheng ^{[2
]}

Sun, Cheng-Jun ^{[3
]}

Ren, Yang ^{[3
]}

Lu, Yuhao ^{[4
]}

Yao, Yan ^{[1
,5
]}

机构：

[1] Univ Houston, Dept Elect & Comp Engn, Mat Sci & Engn Program, Houston, TX 77204 USA

[2] Pacific Northwest Natl Lab, Energy Proc & Mat Div, Richland, WA 99354 USA

[3] Argonne Natl Lab, Xray Sci Div, 9700 S Cass Ave, Argonne, IL 60439 USA

[4] Sharp Labs Amer, Camas, WA 98607 USA

[5] Univ Houston, Texas Ctr Superconduct, Houston, TX 77204 USA

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 53期

基金：

美国国家科学基金会;

关键词：

ION BATTERIES; CATHODE; STORAGE; ELECTROLYTE; LITHIUM; HEXACYANOFERRATE; COMPLEX; CARBON;

D O I：

10.1039/c6cc03081e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a high performance magnesium-sodium hybrid battery utilizing a magnesium-sodium dual-salt electrolyte, a magnesium anode, and a Berlin green cathode. The cell delivers an average discharge voltage of 2.2 V and a reversible capacity of 143 mA h g(-1). We also demonstrate the cell with an energy density of 135 W h kg(-1) and a high power density of up to 1.67 kW kg(-1).

引用

页码：8263 / 8266

页数：4

共 24 条

[1] Prototype systems for rechargeable magnesium batteries [J].

Aurbach, D ;

Lu, Z ;

Schechter, A ;

Gofer, Y ;

Gizbar, H ;

Turgeman, R ;

Cohen, Y ;

Moshkovich, M ;

Levi, E .

NATURE, 2000, 407 (6805) :724-727

[2] New Mechanistic Insights on Na-Ion Storage in Nongraphitizable Carbon [J].

Bommier, Clement ;

Surta, Todd Wesley ;

Dolgos, Michelle ;

Ji, Xiulei .

NANO LETTERS, 2015, 15 (09) :5888-5892

[3] Elucidating the structure of the magnesium aluminum chloride complex electrolyte for magnesium-ion batteries [J].

Canepa, Pieremanuele ;

Jayaraman, Saivenkataraman ;

Cheng, Lei ;

Rajput, Nav Nidhi ;

Richards, William D. ;

Gautam, Gopalakrishnan Sai ;

Curtiss, Larry A. ;

Persson, Kristin A. ;

Ceder, Gerbrand .

ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (12) :3718-3730

[4] Highly active electrolytes for rechargeable Mg batteries based on a [Mg2(μ-Cl)2]2+ cation complex in dimethoxyethane [J].

Cheng, Yingwen ;

Stolley, Ryan M. ;

Han, Kee Sung ;

Shao, Yuyan ;

Arey, Bruce W. ;

Washton, Nancy M. ;

Mueller, Karl T. ;

Helm, Monte L. ;

Sprenkle, Vincent L. ;

Liu, Jun ;

Li, Guosheng .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (20) :13307-13314

[5] High performance batteries based on hybrid magnesium and lithium chemistry [J].

Cheng, Yingwen ;

Shao, Yuyan ;

Ji-Guang Zhang ;

Sprenkle, Vincent L. ;

Liu, Jun ;

Li, Guosheng .

CHEMICAL COMMUNICATIONS, 2014, 50 (68) :9644-9646

[6] Electrochemically stable cathode current collectors for rechargeable magnesium batteries [J].

Cheng, Yingwen ;

Liu, Tianbiao ;

Shao, Yuyan ;

Engelhard, Mark H. ;

Liu, Jun ;

Li, Guosheng .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (08) :2473-2477

[7] Improved electrolyte solutions for rechargeable magnesium batteries [J].

Gofer, Y ;

Chusid, O ;

Gizbar, H ;

Viestfrid, Y ;

Gottlieb, HE ;

Marks, V ;

Aurbach, D .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (05) :A257-A260

[8] Microscopic properties of lithium, sodium, and magnesium battery anode materials related to possible dendrite growth [J].

Jaeckle, Markus ;

Gross, Axel .

JOURNAL OF CHEMICAL PHYSICS, 2014, 141 (17)

[9] Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage [J].

Liang, Yanliang ;

Yoo, Hyun Deog ;

Li, Yifei ;

Shuai, Jing ;

Calderon, Hector A. ;

Hernandez, Francisco Carlos Robles ;

Grabow, Lars C. ;

Yao, Yan .

NANO LETTERS, 2015, 15 (03) :2194-2202

[10] Prussian blue: a new framework of electrode materials for sodium batteries [J].

Lu, Yuhao ;

Wang, Long ;

Cheng, Jinguang ;

Goodenough, John B. .

CHEMICAL COMMUNICATIONS, 2012, 48 (52) :6544-6546

← 1 2 3 →