Terpolymerization of CO2 with propylene oxide and ε-caprolactone using zinc glutarate catalyst

被引:76
作者
Hwang, YT
Jung, JW
Ree, M
Kim, H
机构
[1] Pohang Univ Sci & Technol, Polymer Res Inst, Sch Environm Sci & Engn, Dept Chem,Ctr Integrated Mol Syst,BK21 Program, Pohang 790784, South Korea
[2] Pohang Univ Sci & Technol, Div Mol & Life Sci, Pohang 790784, South Korea
关键词
CARBON-DIOXIDE; ALTERNATING COPOLYMERIZATION; DERIVATIVES; COMPLEXES; EPOXIDE;
D O I
10.1021/ma034498b
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Zinc glutarate-catalyzed terpolymerization of CO2 with PO and ε-caprolactone (CL) was carried out. Aliphatic carbonate-ester terpolymers with excellent enzymatic and biodegradability were produced.
引用
收藏
页码:8210 / 8212
页数:3
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