Poly(naphthalenehydrocarbyne): synthesis, characterization, and application to preparation of thin diamond films

被引：5
作者：
Bulychev, B. M. [1 ]
Zvukova, T. M. [1 ]
Sizov, A. I. [1 ]
Aleksandrov, A. F. [2 ]
Korobov, Yu. A. [2 ]
Kanzyuba, M. V. [3 ]
Khomich, A. V. [4 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119991, Russia
[3] Russian Acad Sci, AM Prokhorov Inst Gen Phys, Moscow 119991, Russia
[4] VA Kotelnikov Inst Radio Engn & Elect, Fryazino 141190, Moscow Region, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2010年 / 59卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
diamond precursor; poly(carbynes); nucleation; diamond films; POLYMER PRECURSOR PROCESS; CARBON; SUBSTRATE; GROWTH;
D O I：
10.1007/s11172-010-0303-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The diamond phase precursor, viz., poly(naphthalenehydrocarbyne) (1), was prepared. Its disordered structure is built of CH fragments with sp(3)-hybridized carbon atoms, and arene fragments are inserted in the structure. The use of 1 in the process of diamond layer deposition makes it possible to prepare highly qualitative thin diamond coatings with low roughness and good optical properties.
引用
收藏
页码：1724 / 1728
页数：5
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