Photoluminescence and X-ray absorption near edge structure of Eu ions doped SiO2 thin films

被引:5
作者
Liu, F
Zhu, M
Liu, T
机构
[1] Univ Sci & Technol China, Grad Sch, Beijing 100039, Peoples R China
[2] State Key Lab Mat Chem & Applicat, Beijing 100039, Peoples R China
[3] Inst High Energy Phys, Synchrotron Radiat Lab, Beijing 100039, Peoples R China
来源
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY | 2001年 / 81卷 / 1-3期
基金
中国国家自然科学基金;
关键词
Eu ions; SiO2; photoluminescence; XANES;
D O I
10.1016/S0921-5107(00)00732-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Eu doped SiO2 thin films, SiO2(Eu), were prepared by implanting Eu ions into thermal growth SiO2 thin films and co-sputtering of SiO2 and Eu2O3. The red light emission (604 nm) at room temperature from as prepared and annealed SiOz(Eu) films was observed, which is corresponding to the D-5(0)-F-7(J) transitions of Eu3+. The blue light emission (443 nm) corresponding to f-d transition of Eu2+ appeared after annealing at high temperature in N-2 accompanied by a decrease in intensity of red light. It indicates the conversion of Eu3+ to Eu2+. The Eu-L-3-edge X-ray absorption near edge structure (XANES) spectra show the doublet peak structure with energy difference of 7 eV, which confirms the conversion of Eu3+ to Eu2+ at high annealing temperature (Ta) in N-2. (C) 2001 Elsevier Science S.A. AII rights reserved.
引用
收藏
页码:179 / 181
页数:3
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