Precise size control of hydrophobic gold nanoparticles in the 2-5 nm range

被引:4
作者
Goldmann, Claire [1 ]
Moretti, Chiara [2 ]
Mahler, Benoit [3 ]
Abecassis, Benjamin [2 ]
Imperor-Clerc, Marianne [1 ]
Pansu, Brigitte [1 ]
机构
[1] Univ Paris Saclay, Lab Phys Solides, CNRS, F-91405 Orsay, France
[2] Univ Claude Bernard, Univ Lyon, Lab Chim, Ecole Normale Super Lyon,UMR 5182, F-69007 Lyon, France
[3] Univ Claude Bernard Lyon 1, Univ Lyon, Inst Lumiere Matiere, CNRS, F-69622 Villeurbanne, France
关键词
SCATTERING FUNCTIONS; NUCLEATION; PHASE;
D O I
10.1039/d1cc05351e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a seed-mediated synthesis strategy to control the size of gold nanoparticles at the atomic scale in the 2-5 nm size range. Starting from 2 nm seeds, a regrowth in organic solvent with a designed amount of precursor can achieve in a predictive fashion a precise mean size with a 0.3 nm resolution. We show that these monodisperse nanoparticles assemble into a 2D hexagonal lattice over a distance that can span tens of micrometers.
引用
收藏
页码:12512 / 12515
页数:4
相关论文
共 19 条
  • [1] Kinetically Controlled Seeded Growth Synthesis of Citrate-Stabilized Gold Nanoparticles of up to 200 nm: Size Focusing versus Ostwald Ripening
    Bastus, Neus G.
    Comenge, Joan
    Puntes, Victor
    [J]. LANGMUIR, 2011, 27 (17) : 11098 - 11105
  • [2] SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM
    BRUST, M
    WALKER, M
    BETHELL, D
    SCHIFFRIN, DJ
    WHYMAN, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) : 801 - 802
  • [3] From gold nanobipyramids to nanojavelins for a precise tuning of the plasmon resonance to the infrared wavelengths: experimental and theoretical aspects
    Chateau, D.
    Liotta, A.
    Vadcard, F.
    Navarro, J. R. G.
    Chaput, F.
    Lerme, J.
    Lerouge, F.
    Parola, S.
    [J]. NANOSCALE, 2015, 7 (05) : 1934 - 1943
  • [4] Gold Nanoparticle Internal Structure and Symmetry Probed by Unified Small-Angle X-ray Scattering and X-ray Diffraction Coupled with Molecular Dynamics Analysis
    Fleury, Blaise
    Cortes-Huerto, Robinson
    Tache, Olivier
    Testard, Fabienne
    Menguy, Nicolas
    Spalla, Olivier
    [J]. NANO LETTERS, 2015, 15 (09) : 6088 - 6094
  • [5] Disentangling the effect of seed size and crystal habit on gold nanoparticle seeded growth
    Gonzalez-Rubio, Guillermo
    de Oliveira, Thais Milagres
    Altantzis, Thomas
    La Porta, Andrea
    Guerrero-Martinez, Andres
    Bals, Sara
    Scarabelli, Leonardo
    Liz-Marzan, Luis. M.
    [J]. CHEMICAL COMMUNICATIONS, 2017, 53 (82) : 11360 - 11363
  • [6] Which Forces Control Supracrystal Nucleation in Organic Media?
    Goubet, Nicolas
    Richardi, Johannes
    Albouy, Pierre-Antoine
    Pileni, Marie-Paule
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (14) : 2693 - 2704
  • [7] Determination of size and concentration of gold nanoparticles from UV-Vis spectra
    Haiss, Wolfgang
    Thanh, Nguyen T. K.
    Aveyard, Jenny
    Fernig, David G.
    [J]. ANALYTICAL CHEMISTRY, 2007, 79 (11) : 4215 - 4221
  • [8] A simple large-scale synthesis of nearly monodisperse gold and silver nanoparticles with adjustable sizes and with exchangeable surfactants
    Hiramatsu, H
    Osterloh, FE
    [J]. CHEMISTRY OF MATERIALS, 2004, 16 (13) : 2509 - 2511
  • [9] Single-phase and gram-scale routes toward nearly monodisperse Au and other noble metal nanocrystals
    Jana, NR
    Peng, XG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (47) : 14280 - 14281
  • [10] Evidence for seed-mediated nucleation in the chemical reduction of gold salts to gold nanoparticles
    Jana, NR
    Gearheart, L
    Murphy, CJ
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (07) : 2313 - 2322