Precise size control of hydrophobic gold nanoparticles in the 2-5 nm range

被引:4
作者
Goldmann, Claire [1 ]
Moretti, Chiara [2 ]
Mahler, Benoit [3 ]
Abecassis, Benjamin [2 ]
Imperor-Clerc, Marianne [1 ]
Pansu, Brigitte [1 ]
机构
[1] Univ Paris Saclay, Lab Phys Solides, CNRS, F-91405 Orsay, France
[2] Univ Claude Bernard, Univ Lyon, Lab Chim, Ecole Normale Super Lyon,UMR 5182, F-69007 Lyon, France
[3] Univ Claude Bernard Lyon 1, Univ Lyon, Inst Lumiere Matiere, CNRS, F-69622 Villeurbanne, France
关键词
SCATTERING FUNCTIONS; NUCLEATION; PHASE;
D O I
10.1039/d1cc05351e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a seed-mediated synthesis strategy to control the size of gold nanoparticles at the atomic scale in the 2-5 nm size range. Starting from 2 nm seeds, a regrowth in organic solvent with a designed amount of precursor can achieve in a predictive fashion a precise mean size with a 0.3 nm resolution. We show that these monodisperse nanoparticles assemble into a 2D hexagonal lattice over a distance that can span tens of micrometers.
引用
收藏
页码:12512 / 12515
页数:4
相关论文
共 19 条
[1]   Kinetically Controlled Seeded Growth Synthesis of Citrate-Stabilized Gold Nanoparticles of up to 200 nm: Size Focusing versus Ostwald Ripening [J].
Bastus, Neus G. ;
Comenge, Joan ;
Puntes, Victor .
LANGMUIR, 2011, 27 (17) :11098-11105
[2]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[3]   From gold nanobipyramids to nanojavelins for a precise tuning of the plasmon resonance to the infrared wavelengths: experimental and theoretical aspects [J].
Chateau, D. ;
Liotta, A. ;
Vadcard, F. ;
Navarro, J. R. G. ;
Chaput, F. ;
Lerme, J. ;
Lerouge, F. ;
Parola, S. .
NANOSCALE, 2015, 7 (05) :1934-1943
[4]   Gold Nanoparticle Internal Structure and Symmetry Probed by Unified Small-Angle X-ray Scattering and X-ray Diffraction Coupled with Molecular Dynamics Analysis [J].
Fleury, Blaise ;
Cortes-Huerto, Robinson ;
Tache, Olivier ;
Testard, Fabienne ;
Menguy, Nicolas ;
Spalla, Olivier .
NANO LETTERS, 2015, 15 (09) :6088-6094
[5]   Disentangling the effect of seed size and crystal habit on gold nanoparticle seeded growth [J].
Gonzalez-Rubio, Guillermo ;
de Oliveira, Thais Milagres ;
Altantzis, Thomas ;
La Porta, Andrea ;
Guerrero-Martinez, Andres ;
Bals, Sara ;
Scarabelli, Leonardo ;
Liz-Marzan, Luis. M. .
CHEMICAL COMMUNICATIONS, 2017, 53 (82) :11360-11363
[6]   Which Forces Control Supracrystal Nucleation in Organic Media? [J].
Goubet, Nicolas ;
Richardi, Johannes ;
Albouy, Pierre-Antoine ;
Pileni, Marie-Paule .
ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (14) :2693-2704
[7]   Determination of size and concentration of gold nanoparticles from UV-Vis spectra [J].
Haiss, Wolfgang ;
Thanh, Nguyen T. K. ;
Aveyard, Jenny ;
Fernig, David G. .
ANALYTICAL CHEMISTRY, 2007, 79 (11) :4215-4221
[8]   A simple large-scale synthesis of nearly monodisperse gold and silver nanoparticles with adjustable sizes and with exchangeable surfactants [J].
Hiramatsu, H ;
Osterloh, FE .
CHEMISTRY OF MATERIALS, 2004, 16 (13) :2509-2511
[9]   Single-phase and gram-scale routes toward nearly monodisperse Au and other noble metal nanocrystals [J].
Jana, NR ;
Peng, XG .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (47) :14280-14281
[10]   Evidence for seed-mediated nucleation in the chemical reduction of gold salts to gold nanoparticles [J].
Jana, NR ;
Gearheart, L ;
Murphy, CJ .
CHEMISTRY OF MATERIALS, 2001, 13 (07) :2313-2322