Metal-Organic Frameworks from Edible Natural Products

被引：601
作者：
Smaldone, Ronald A. [1 ]
Forgan, Ross S. [1 ]
Furukawa, Hiroyasu [2 ]
Gassensmith, Jeremiah J. [1 ]
Slawin, Alexandra M. Z. [3 ]
Yaghi, Omar M. [2 ]
Stoddart, J. Fraser [1 ]
机构：
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[3] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 46期
基金：
美国国家科学基金会; 英国工程与自然科学研究理事会;
关键词：
alkali metals; cyclodextrins; metal-organic frameworks; sorption; X-ray diffraction; GAS-CHROMATOGRAPHIC SEPARATION; HYDROGEN STORAGE; CARBON-DIOXIDE; RETICULAR CHEMISTRY; CRYSTAL-STRUCTURE; XYLENE ISOMERS; HIGH-CAPACITY; ADSORPTION; DESIGN; SELECTIVITY;
D O I：
10.1002/anie.201002343
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Let them eat MOFs: Take a spoonful of sugar (γ-cyclodextrin to be precise), a pinch of salt (most alkali metal salts will suffice), and a swig of alcohol (Everclear fits the bill), and you have a robust, renewable, nanoporous (Langmuir surface area 1320-m2-g-1) metal organic framework for breakfast (CD-MOF-1; see picture, C-gray, O-red, K-purple; yellow sphere: pore). © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8630 / 8634
页数：5
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