High Capacity Positive Electrode Material for Room Temperature Na Ion Battery: NaxMn2/3Co1/6Ni1/6O2

A layered compound, NaxMn2/3Co1/6Ni1/6O2 (NMCN), prepared by a solid-state reaction, served as a high capacity positive electrode material with the reversible capacity of ca. 200 mA.h.g(-1) using a Na foil as the counter electrode. A high-resolution synchrotron X-ray diffraction (XRD) analysis revealed that, whereas the NMCN sample had the P3 structure (R3m) when the precursor was heated below 700 degrees C, the P-2 structure (P6(3)/mmc) was obtained when heated above 800 degrees C. The latter excels over the former in both capacity and cycle stability; i.e., the initial discharge capacities and potentials of the P2 and P3-NMCN were 216 mA.h.g(-1), 2.87 V vs. Na+/Na and 206 mA.h.g(-1), 2.78 V vs. Na+/Na, respectively. The P2-MNCN retained 80% of its initial discharge capacity while the P3-NMCN dropped to 69% after 30 cycles in the potential range of 1.0-4.5 V vs. Na+/Na. An in-situ XRD analysis revealed that the lattice volume of the P2-NMCN contracts and expands by 20% during the charge and discharge (i.e., Na extraction and insertion) without drastically changing its crystallographic structure. (C) 2015 The Electrochemical Society. All rights reserved.