Synthesis and crystal structure of one-dimensional chain complexes [K(18-C-6)]2[M(mnt)2](M = Zn, Hg)

被引：0

作者：

Wang, DQ

He, GF

Qiu, LL

Dou, JM ^{[1
]}

机构：

[1] Liaocheng Univ, Dept Chem, Liaocheng 252000, Peoples R China

[2] Taishan Coll, Dept Chem, Tai An 271021, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2003年 / 19卷 / 03期

关键词：

one-dimensional chain; crown ether; mnt complex; 18-crown-6; crystal structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of 18-crown-6 with each of K-2 [M (mnt)(2)] (M = Zn, Hg; mnt = 1, 2-dicyanoethene-1, 2-dithiolate, C2S2(CN)(2)(2-)) were studied and novel complexes [K(18-C-6)](2)[Zn(mnt)(2)](1) and [K(18-C-6)](2) [Hg(mnt)(2)](2) were characterized by elemental analysis, IR spectrum and X-ray diffraction analysis. Complex I displays a one-dimensional chain of [K(18-C-6)](2)[Zn(mnt)(2)] bridged by K-O interactions between adjacent [K(18-C-6)](+) units. Complex 2 is also a one-dimensional chain of [K(18-C-6)](2)[Hg(mnt)(2)] bridged by K...S weak interactions between adjacent [K(18-C-6)](+) and [Hg(mnt)(2)](2-).

引用

页码：263 / 268

页数：6

共 32 条

[1] THE CHEMISTRY AND SOLID-STATE PROPERTIES OF NICKEL, PALLADIUM AND PLATINUM BIS(MALEONITRILEDITHIOLATE) COMPOUNDS [J].