Photocatalytic reduction of CO2 with H2O using perovskite CaxTiyO3

被引:49
作者
Kwak, Byeong Sub [1 ]
Kang, Misook [1 ]
机构
[1] Yeungnam Univ, Coll Sci, Dept Chem, Gyongsan 712749, Gyeongbuk, South Korea
关键词
Photo-reduction; CO2; Photocatalysis; Perovskite; CaTiO3; CARBON-DIOXIDE; DOPED TIO2; PHOTOREDUCTION; COMPOSITE; CONVERSION; CH4; NANOPARTICLES; ADSORPTION; CATALYSTS; CU/TIO2;
D O I
10.1016/j.apsusc.2015.02.078
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study is focused on the photoreduction of CO2 into CH4 using CaxTiyO3 perovskite nanoparticles. CaxTiyO3 nanoparticles were successfully synthesized by a hydrothermal method. The structure and property of CaxTiyO3 were characterized using XRD, UV-vis, PL, and BET techniques. The photoreduction of CO2 was performed with UV-lamp (6 W cm(-2)) irradiation. The gas products were analyzed in a gas chromatograph equipped with FID and TCD detectors. The methane formation rate from CO2 and H2O was 17 mu mol/ g for 7 h using 0.2 g of Ca1.00Ti1.00O3. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:138 / 144
页数:7
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