Synthesis and properties of polyester dendrimers bearing carbazole groups in their periphery

被引:0
作者
Bo, ZS [1 ]
Zhang, WK [1 ]
Zhang, X [1 ]
Zhang, CM [1 ]
Shen, JC [1 ]
机构
[1] Jilin Univ, Dept Chem, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China
关键词
D O I
10.1002/(SICI)1521-3935(19980701)199:7<1323::AID-MACP1323>3.0.CO;2-J
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polyester dendrimers bearing carbazole units at their peripheries were synthesized by attacking 3,5-bis[4-(9-carbazolyl)butoxy]benzoic acid to the peripherical phenoxy groups. The phenoxy-terminated polyester dendrimers were synthesized by hydrogenation of the corresponding benzyloxy-terminated polyester dendrimers. The structure of the synthesized compounds was confirmed with IR, (NMR)-N-1, MALDI-TOF MS and GPC. The reaction conditions for attaching 3,5-bis[4-(9-carbazolyl)butoxy]benzoic acid to the peripherical phenoxy groups of polyester dendrimers were studied. Fluorescence spectra studies showed that there exist strong intramolecular interactions in the carbazole dendrimer molecules.
引用
收藏
页码:1323 / 1327
页数:5
相关论文
共 26 条
[1]   GLOBULAR CARBOHYDRATE MACROMOLECULE SUGAR BALLS .1. SYNTHESIS OF NOVEL SUGAR-PERSUBSTITUTED POLY(AMIDO AMINE) DENDRIMERS [J].
AOI, K ;
ITOH, K ;
OKADA, M .
MACROMOLECULES, 1995, 28 (15) :5391-5393
[2]   Fullerenes finally score as Nobel committee honours chemists [J].
Ball, P .
NATURE, 1996, 383 (6601) :561-561
[3]   CATALYSIS - ELECTRON-TRANSFER BRANCHES OUT [J].
BARD, AJ .
NATURE, 1995, 374 (6517) :13-13
[4]  
BO Z, 1997, J CHEM SOC P1, P2391
[5]  
BRYCE MR, 1994, ANGEW CHEM INT EDIT, V33, P1761, DOI 10.1002/anie.199417611
[6]  
Dandliker PJ, 1995, ANGEW CHEM INT EDIT, V34, P2725
[7]  
DANDLIKER PJ, 1994, ANGEW CHEM INT EDIT, V33, P1739, DOI 10.1002/anie.199417391
[8]   AN ELECTRICALLY CONDUCTING DENDRIMER [J].
DUAN, RG ;
MILLER, LL ;
TOMALIA, DA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (43) :10783-10784
[9]  
FILLAUT JL, 1994, ANGEW CHEM INT EDIT, V33, P2460
[10]   FUNCTIONAL POLYMERS AND DENDRIMERS - REACTIVITY, MOLECULAR ARCHITECTURE, AND INTERFACIAL ENERGY [J].
FRECHET, JMJ .
SCIENCE, 1994, 263 (5154) :1710-1715