Effect of peptide orientation on electron transfer

被引：20

作者：

Chaudhry, Bushra R. ^{[1
]}

Wilton-Ely, James D. E. T. ^{[1
]}

Tabor, Alethea B. ^{[1
]}

Caruana, Daren J. ^{[1
]}

机构：

[1] UCL, Dept Chem, London WC1H 0AJ, England

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2010年 / 12卷 / 34期

基金：

英国工程与自然科学研究理事会;

关键词：

ALKANETHIOL MONOLAYERS; DISTANCE DEPENDENCE; TRANSFER KINETICS; HELICAL PEPTIDES; FERROCENE; GOLD;

D O I：

10.1039/c0cp00226g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have developed a methodology for the in situ derivatisation of histidine residues in self-assembled monolayers of peptides with redox-active groups, and have shown by electrochemical methods that the average dipole of peptide films on gold affects the heterogeneous electron transfer properties.

引用

收藏

页码：9996 / 9998

页数：3

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