Mono- and bimetallic (Ru-Co) polymeric catalysts for levulinic acid hydrogenation

被引：20

作者：

Grigorev, Maxim E. ^{[1
]}

Mikhailov, Stepan P. ^{[1
]}

Bykov, Alexey, V ^{[1
]}

Sidorov, Alexander, I ^{[1
]}

Tiamina, Irina Yu ^{[1
]}

Vasiliev, Alexandre L. ^{[2
]}

Nikoshvili, Linda Zh ^{[1
]}

Matveeva, Valentina G. ^{[1
,3
]}

Meneghetti, Simoni M. Plentz ^{[4
]}

Sulman, Mikhail G. ^{[1
]}

Sulman, Esther M. ^{[1
]}

机构：

[1] Tver Tech Univ, Dept Biotechnol Chem & Standardizat, Tver 170026, Russia

[2] Kurchatov Inst, Natl Res Ctr, Moscow 123182, Russia

[3] Tver State Univ, Reg Technol Ctr, Tver 170100, Russia

[4] Univ Fed Alagoas, Inst Quim & Biotecnol, Av Lourival de Melo Mota S-N,Cidade Univ, BR-57072970 Maceio, Alagoas, Brazil

来源：

CATALYSIS TODAY | 2021年 / 378卷

基金：

俄罗斯基础研究基金会; 俄罗斯科学基金会;

关键词：

Levulinic acid; Gamma-valerolactone; Hyper-crosslinked polystyrene; Ruthenium; Cobalt; Catalytic hydrogenation; GAMMA-VALEROLACTONE; SELECTIVE HYDROGENATION; HYPERCROSSLINKED POLYSTYRENE; BIOMASS; CONVERSION; EFFICIENT; PRECURSOR; CHEMICALS; PLATFORM; SOLVENT;

D O I：

10.1016/j.cattod.2020.11.023

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Levulinic acid (LA) is one of the substances, which can be obtained from cellulosic biomass via acid hydrolysis and serves as a precursor in the synthesis of gamma-valerolactone (GVL) - platform chemical for so-called valeric fuels. This work is devoted to the study of catalytic conversion of LA to GVL using mono-(Ru) and bimetallic (RuCo) catalysts based on ruthenium-containing nanoparticles immobilized in hyper-crosslinked polystyrene (HPS). It was shown that RuO2 nanoparticles are an active phase of HPS-based Ru catalysts, which allow nearly 100 % yield of GVL at 120 degrees C and 2 MPa of hydrogen partial pressure for the reaction time 60 min. Introduction of cobalt in catalyst composition in a proper amount (Ru-to-Co weight ratio is 30) was found to result in Ru redistribution inside the polymeric support and, in turn, to the increase of reaction rate of LA hydrogenation.

引用

页码：167 / 175

页数：9

共 39 条

[1] Exploring the ruthenium catalysed synthesis of γ-valerolactone in alcohols and utilisation of mild solvent-free reaction conditions [J].

Al-Shaal, Mohammad G. ;

Wright, William R. H. ;

Palkovits, Regina .

GREEN CHEMISTRY, 2012, 14 (05) :1260-1263

[2] Production of liquid hydrocarbon fuels by catalytic conversion of biomass-derived levulinic acid [J].

Braden, Drew J. ;

Henao, Carlos A. ;

Heltzel, Jacob ;

Maravelias, Christos T. ;

Dumesic, James A. .

GREEN CHEMISTRY, 2011, 13 (07) :1755-1765

[3] Conversion of biomass platform molecules into fuel additives and liquid hydrocarbon fuels [J].

Climent, Maria J. ;

Corma, Avelino ;

Iborra, Sara .

GREEN CHEMISTRY, 2014, 16 (02) :516-547

[4] Green synthesis of gamma-valerolactone (GVL) through hydrogenation of biomass-derived levulinic acid using non-noble metal catalysts: A critical review [J].

Dutta, Shanta ;

Yu, Iris K. M. ;

Tsang, Daniel C. W. ;

Ng, Yun Hau ;

Ok, Yong Sik ;

Sherwood, James ;

Clark, James H. .

CHEMICAL ENGINEERING JOURNAL, 2019, 372 :992-1006

[5] Influence of Sulfuric Acid on the Performance of Ruthenium-based Catalysts in the Liquid-Phase Hydrogenation of Levulinic Acid to γ-Valerolactone [J].

Ftouni, Jamal ;

Genuino, Homer C. ;

Munoz-Murillo, Ara ;

Bruijnincx, Pieter C. A. ;

Weckhuysen, Bert M. .

CHEMSUSCHEM, 2017, 10 (14) :2891-2896

[6] Hydrogenation of Levulinic Acid over Nickel Catalysts Supported on Aluminum Oxide to Prepare γ-Valerolactone [J].

Fu, Jie ;

Sheng, Dong ;

Lu, Xiuyang .

CATALYSTS, 2016, 6 (01)

[7] A sustainable process for the production of γ-valerolactone by hydrogenation of biomass-derived levulinic acid [J].

Galletti, Anna Maria Raspolli ;

Antonetti, Claudia ;

De Luise, Valentina ;

Martinelli, Marco .

GREEN CHEMISTRY, 2012, 14 (03) :688-694

[8] Catalytic Hydrogenation of Renewable Levulinic Acid to γ-Valerolactone: Insights into the Influence of Feed Impurities on Catalyst Performance in Batch and Flow Reactors [J].

Genuino, Homer C. ;

de Bovenkamp, Henk H. van ;

Wilbers, Erwin ;

Winkelman, Jozef G. M. ;

Goryachev, Andrey ;

Hofmann, Jan P. ;

Hensen, Emiel J. M. ;

Weckhuysen, Bert M. ;

Bruijnincx, Pieter C. A. ;

Heeres, Hero J. .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (15) :5903-5919

[9] Hydrous ruthenium oxide: A new generation remarkable catalyst precursor for energy efficient and sustainable production of γ-valerolactone from levulinic acid in aqueous medium [J].

Gundekari, Sreedhar ;

Srinivasan, Kannan .

APPLIED CATALYSIS A-GENERAL, 2019, 569 :117-125

[10] Leaching of copper oxide with different acid solutions [J].

Habbache, N. ;

Alane, N. ;

Djerad, S. ;

Tifouti, L. .

CHEMICAL ENGINEERING JOURNAL, 2009, 152 (2-3) :503-508

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