Preparation and One-Electron Oxidation of Decabromoferrocene

被引：10

作者：

Rupf, Susanne M. ^{[1
]}

Dimitrova, Irina S. ^{[1
]}

Schroeder, Gabriel ^{[1
]}

Malischewski, Moritz ^{[1
]}

机构：

[1] Free Univ Berlin, D-14195 Berlin, Germany

来源：

ORGANOMETALLICS | 2022年 / 41卷 / 10期

关键词：

PERMERCURATED ARENES; CRYSTAL-STRUCTURE; FERROCENES; ELECTROCHEMISTRY; DECAMETHYLFERROCENE; IODOFERROCENE; STABILITY; SALTS;

D O I：

10.1021/acs.organomet.2c00157

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report an improved synthesis as well as a spectroscopical, structural, and electrochemical characterization of decabromoferrocene (FeC10Br10) and relevant side products. One-electron oxidation of decabromoferrocene (E-1/2 = 1.095 V vs FeCp20/+) was achieved by AsF5 in liquid SO2. The crystal structure of decabromoferrocenium hexafluoroarsenate, [FeC10Br10][AsF6], represents the first example of an isolated and structurally characterized perhalogenated ferrocenium salt.

引用

收藏

页码：1261 / 1267

页数：7

相关论文

共 50 条

[31] The Me3NB12Cl11• Radical: A Strong One-Electron Oxidizing Agent [J].

Bertocco, Philipp ;

Bolli, Christoph ;

Derendorf, Janis ;

Jenne, Carsten ;

Klein, Axel ;

Stirnat, Kathrin .

CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (45) :16032-16036

[32] Evidence for a One-Electron Mechanistic Regime in Dirhodium-Catalyzed Intermolecular C-H Amination [J].

Kornecki, Katherine P. ;

Berry, John F. .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (21) :5827-5832

[33] The one-electron reduction of a multi-centered iron(III) polyoxometallate. A pulse radiolysis study [J].

Popivker, Inna ;

Zilbermann, Israel ;

Maimon, Eric ;

Cohen, Haim ;

Meyerstein, Dan .

INORGANIC CHEMISTRY COMMUNICATIONS, 2011, 14 (09) :1390-1392

[34] One-Electron Reduction of 2-Mono(2,6-diisopropylphenylimino)acenaphthene-1-one (dpp-mian) [J].

Lukoyanov, Anton N. ;

Ulivanova, Elena A. ;

Razborov, Danila A. ;

Khrizanforova, Vera V. ;

Budnikova, Yulia H. ;

Makarov, Sergey G. ;

Rumyantcev, Roman, V ;

Ketkov, Sergey Y. ;

Fedushkin, Igor L. .

CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (15) :3858-3866

[35] Electrochemical oxidation of 1,4-dialkoxybenzenes in organic media. Reversible one-electron process in a methylene chloride/trifluoroacetic acid mixture and electropolymerization reaction in dry acetonitrile [J].

Fabre, B ;

Michelet, K ;

Simonet, N ;

Simonet, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 425 (1-2) :67-75

[36] Achieving Low Overpotential Li-O2 Battery Operations by Li2O2 Decomposition through One-Electron Processes [J].

Xie, Jin ;

Dong, Qi ;

Madden, Ian ;

Yao, Xiahui ;

Cheng, Qingmei ;

Dornath, Paul ;

Fan, Wei ;

Wang, Dunwei .

NANO LETTERS, 2015, 15 (12) :8371-8376

[37] Spectroelectrochemical one-electron reduction product of (TPP)Zn in nonaqueous media? Not always the expected porphyrin π-anion radical [J].

Osterloh, W. Ryan ;

Fang, Yuanyuan ;

Ou, Zhongping ;

Kadish, Karl M. .

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2022, 26 (06N07) :495-502

[38] First and Second Reductions in an Aprotic Solvent: Comparing Computational and Experimental One-Electron Reduction Potentials for 345 Quinones [J].

Elhajj, Sarah ;

Gozem, Samer .

JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2024, 20 (14) :6227-6240

[39] Calculation of One-Electron Redox Potentials Revisited. Is It Possible to Calculate Accurate Potentials with Density Functional Methods? [J].

Roy, Lindsay E. ;

Jakubikova, Elena ;

Guthrie, M. Graham ;

Batista, Enrique R. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (24) :6745-6750

[40] Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted dlquinoxalino[2,3-a:2′,3′-c]phenazine ligands [J].

Ghumaan, Sandeep ;

Sarkar, Biprajit ;

Patil, Mahendra P. ;

Fiedler, Jan ;

Sunoj, Raghavan B. ;

Kaim, Wolfgang ;

Lahiri, Goutam Kumar .

POLYHEDRON, 2007, 26 (13) :3409-3418

← 1 2 3 4 5 →