Preparation and One-Electron Oxidation of Decabromoferrocene

被引：10

作者：

Rupf, Susanne M. ^{[1
]}

Dimitrova, Irina S. ^{[1
]}

Schroeder, Gabriel ^{[1
]}

Malischewski, Moritz ^{[1
]}

机构：

[1] Free Univ Berlin, D-14195 Berlin, Germany

来源：

ORGANOMETALLICS | 2022年 / 41卷 / 10期

关键词：

PERMERCURATED ARENES; CRYSTAL-STRUCTURE; FERROCENES; ELECTROCHEMISTRY; DECAMETHYLFERROCENE; IODOFERROCENE; STABILITY; SALTS;

D O I：

10.1021/acs.organomet.2c00157

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report an improved synthesis as well as a spectroscopical, structural, and electrochemical characterization of decabromoferrocene (FeC10Br10) and relevant side products. One-electron oxidation of decabromoferrocene (E-1/2 = 1.095 V vs FeCp20/+) was achieved by AsF5 in liquid SO2. The crystal structure of decabromoferrocenium hexafluoroarsenate, [FeC10Br10][AsF6], represents the first example of an isolated and structurally characterized perhalogenated ferrocenium salt.

引用

收藏

页码：1261 / 1267

页数：7

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