Metallic nanosponges for energy storage and conversion applications

被引:9
作者
Hemanth, N. R. [1 ]
Mohili, Ranjit D. [2 ]
Patel, Monika [2 ]
Jadhav, Arvind H. [3 ]
Lee, Kwangyeol [4 ]
Chaudhari, Nitin K. [2 ]
机构
[1] Natl Inst Technol Karnataka NITK, Dept Met & Mat Engn, Surathkal, Karnataka, India
[2] Pandit Deendayal Energy Univ, Sch Technol, Dept Chem, Gandhinagar 382007, Gujarat, India
[3] Jain Univ, Ctr Nano & Mat Sci CNMS, Jain Global Campus, Bangalore 562112, Karnataka, India
[4] Korea Univ, Res Inst Nat Sci, Dept Chem, Seoul 02841, South Korea
基金
新加坡国家研究基金会;
关键词
FACILE SOLVOTHERMAL SYNTHESIS; BIMETALLIC ALLOY NANOSPONGES; LIQUID-CRYSTALLINE PHASE; HIGH CATALYTIC-ACTIVITY; HIGH-PERFORMANCE; NANOSTRUCTURED MATERIALS; HYDROGEN EVOLUTION; ANODE MATERIAL; CATHODE MATERIALS; ELECTRODE MATERIALS;
D O I
10.1039/d2ta02057b
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to meet the current energy storage demands, the rational design of novel nanostructured materials is crucial for the improvement of electrochemical storage and conversion performance. Nanostructured materials have shown promising results in various energy harvesting systems, owing to their multifunctional properties such as a large active surface area, mechanical strength, catalytic ability, excellent ion diffusion, and electronic conductivity. To date, the library of nanostructured materials consists of diverse compositions ranging from oxides, dichalcogenides, carbides to graphene-based and lithium alloys with various morphologies such as zero-dimensional (0D), 1D, 2D and 3D nanomaterials. In particular, nanosponges have exhibited unusual three-dimensional architecture that provides rich surface defects and excellent structural stability resulting in improved catalytic activity. Additionally, the large conducting surface, electronic conductivity and pronounced crystalline phase stability of nanosponges have been utilized to improve the electrode performance drastically. Moreover, the unique sponge-like metallic porous network not only reduces the overall weight of the device but also decreases the consumption of metal usage. In this context, this review particularly highlights the recent progress in the synthesis and properties of noble metals and other metal-based sulphide, oxide, hydroxide and phosphide nanosponges, and their application in electrochemical storage and conversion devices.
引用
收藏
页码:14221 / 14246
页数:26
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