Carbon self-doping induced high electronic conductivity and photoreactivity of g-C3N4

被引：709

作者：

Dong, Guohui ^{[1
]}

Zhao, Kun ^{[1
]}

Zhang, Lizhi ^{[1
]}

机构：

[1] Cent China Normal Univ, Key Lab Pesticide & Chem Biol, Minist Educ, Coll Chem, Wuhan 430079, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 49期

基金：

美国国家科学基金会;

关键词：

HYDROGEN-PRODUCTION; BAND-STRUCTURE; PHOTOCATALYST; EVOLUTION;

D O I：

10.1039/c2cc32181e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We theoretically and experimentally demonstrate that carbon self-doping could induce intrinsic electronic and band structure change of g-C3N4 via the formation of delocalized big pi bonds to increase visible light absorption and electrical conductivity as well as surface area and thus enhance both photooxidation and photoreduction activities.

引用

页码：6178 / 6180

页数：3

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