Extraction and separation of multiple platinum group metals from hydrochloric acid solution with sole 1-hexy1-3-methylimidazole-2-thione using microextraction method

被引：18

作者：

Yin, Xiaolu ^{[1
]}

Yi, Huilin ^{[2
]}

Wang, Qi ^{[1
]}

Wang, Yudong ^{[1
]}

Sun, Xu ^{[1
]}

Lv, Cheng ^{[1
]}

Guo, Jinxin ^{[1
]}

Yang, Yanzhao ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Educ Minist, Key Lab Special Funct Aggregate Mat, Jinan 250100, Shandong, Peoples R China

[2] Dalian Univ Technol, Fac Chem Environm & Biol Sci & Technol, Dalian 116024, Peoples R China

来源：

HYDROMETALLURGY | 2017年 / 174卷

基金：

中国国家自然科学基金;

关键词：

Efficient extractant; Microextraction; Separation; Mechanism; Precipitating-calcining method; IMIDAZOLIUM IONIC LIQUIDS; 3-LIQUID-PHASE EXTRACTION; GROUP ELEMENTS; RECOVERY; PALLADIUM; RHODIUM; SYSTEM; COORDINATION; MIXTURES; CAPACITY;

D O I：

10.1016/j.hydromet.2017.10.009

中图分类号：

TF [冶金工业];

学科分类号：

0806 ;

摘要：

In this study, palladium (II), platinum (IV), rhodium (III) and iridium (IV) were sequentially separated with 1-hexyl-3-methylimidazole-2-thione (HMImT) from aqueous hydrochloric acid media by adjustment of hydrochloric acid concentration or in the presence of tin (II) chloride using environmental-friendly microextraction method. It is the first time to use sole extractant to selectively separate four platinum group metals from aqueous solution. Through condition optimization, HMImT shows outstanding extraction capacity (Pd 0.54 mmol/g, Pt 0.14 mmol/g, Rh 0.82 mmol/g) and high extraction percentage to palladium (99.4%), platinum (99.8%), rhodium (99.6%) respectively. The separation coefficient exceeds 10,000 and obtained metals purity reaches 99%. Based on Job's method, FT-IR spectra, UV-vis spectra, H-1 NMR spectra and theoretical natural population analysis (NPA), the anion exchange mechanism of HMImT on Pt (IV) extraction was confirmed. By precipitating calcining method palladium (II), platinum (IV) and rhodium (III) could be recycled in the form of Rh2O3, Pd and Pt2O.

引用

页码：167 / 174

页数：8

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