Synthesis and crystal structure of the first ternary tellurium borate TeB4O8

被引：2

作者：

Ziegler, Raimund ^{[1
]}

Heymann, Gunter ^{[1
]}

Huppertz, Hubert ^{[1
]}

机构：

[1] Univ Innsbruck, Dept Gen Inorgan & Theoret Chem, Innrain 80-82, A-6020 Innsbruck, Austria

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2022年 / 648卷 / 21期

关键词：

borate; tellurate(IV); high-pressure; crystal structure; vibrational spectroscopy; BOND-VALENCE PARAMETERS; REFINEMENT;

D O I：

10.1002/zaac.202200229

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Monoclinic TeB4O8 was obtained in a Walker-type multianvil apparatus at 10 GPa and 1273 K from TeO2 and B2O3. It crystallizes isotypically to the compounds AnB(4)O(8) (An=Th, U) in the space group C2/c (Z=4) with the lattice parameters a=15.6978(8) angstrom, b=4.2284(2) angstrom, c=7.4305(4) angstrom, beta=114.78(1)degrees, and V=447.80(4) angstrom(3). Further, it has been characterized via X-ray diffraction experiments and IR spectroscopy.

引用

页数：6

共 41 条

[1]

Ahmed M.A.K, 2000, DALTON T, P4542

[2] SECONDARY BONDING .10. REFINEMENT OF THE STRUCTURE OF TELLURIUM PHOSPHATE TE2O3.HPO [J].

ALCOCK, NW ;

HARRISON, WD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (JUN) :1809-1811

[3] CRYSTAL-STRUCTURE REFINEMENT OF BASIC TELLURIUM NITRATE - A REFORMULATION AS (TE2O4H)+(NO3)- [J].

ANDERSON, JB ;

RAPPOSCH, MH ;

ANDERSON, CP ;

KOSTINER, E .

MONATSHEFTE FUR CHEMIE, 1980, 111 (04) :789-796

[4]

[Anonymous], APEX3 V 2017 3 0 CEL

[5]

Bourhis LJ, 2015, ACTA CRYSTALLOGR A, V71, P59, DOI [10.1107/S2053273314022207, 10.1107/S205327331402220759]

[6] BOND-VALENCE PARAMETERS FOR SOLIDS [J].

BRESE, NE ;

OKEEFFE, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1991, 47 :192-197

[7] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[8] Hirshfeld atom refinement [J].

Capelli, Silvia C. ;

Buergi, Hans-Beat ;

Dittrich, Birger ;

Grabowsky, Simon ;

Jayatilaka, Dylan .

IUCRJ, 2014, 1 :361-379

[9]

Chukanov N.V., VIBRATIONAL INFRARED

[10]

Dolgikh VA, 1996, ZH NEORG KHIM+, V41, P970

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