Ladder coordination polymers built from [{Re4Q4(CN)12]4- cluster anions (Q= S, Se, Te) and [Gd(phen)(H2O)3Gd(phen)(H2O)2(μ-OH)2]4+ dimeric cationic fragments

被引：15
作者：
Litvinova, Yulia M. [1 ]
Gayfulin, Yakov M. [1 ]
Samsonenko, Denis G. [1 ,2 ]
Bogomyakov, Artem S. [3 ]
Shon, Won Hyuk [4 ,5 ]
Kim, Sung-Jin [4 ]
Rhyee, Jong-Soo [5 ]
Mironov, Yuri V. [1 ]
机构：
[1] Nikolaev Inst Inorgan Chem SB RAS, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
[3] Int Tomog Ctr SB RAS, 3A Inst Skaya Str, Novosibirsk 630090, Russia
[4] Ewha Womans Univ, Dept Chem & Nanosci, Seoul 03760, South Korea
[5] Kyung Hee Univ, Dept Appl Phys, Yongin 17104, Gyeong Gi, South Korea
来源：
POLYHEDRON | 2016年 / 115卷
基金：
新加坡国家研究基金会; 俄罗斯科学基金会;
关键词：
Rhenium cluster; Gadolinium; Coordination polymer; Crystal structure; Magnetic properties; CRYSTAL-STRUCTURE; LANTHANIDE LUMINESCENCE; TRANSITION-METALS; COMPLEXES; DESIGN;
D O I：
10.1016/j.poly.2016.05.013
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new polymeric compounds with general formula {[Gd(phen)(H2O)(3)Gd(phen)(H2O)(2)(mu-OH)(2)] [Re(4)Q(4)(CN)(12)]}.nH(2)O (Q= S0.84Te0.16, n = 0.25 for compound 1; Q= Se, Te, n =1 for compounds 2, 3, respectively) were obtained by self-assembly reaction of [Re(4)Q(4)(CN)(12)](4-) cluster anions, Gd3+ cation and 1,10-phenthroline (phen) in a solvothermal conditions. Compounds were investigated by single-crystal X-ray diffraction, magnetic measurements and thermogravimetric analysis. Structure of compounds consist of non-charged ladder chains formed by alternating [Re4Q4(CN)12]4- cluster anions and dimeric cationic complex [{Gd(phen)(H2O)(3)Gd(phen)(H2O)(2)(mu-OH)(2))](4-) connected through covalent bonds. Chains are packed parallel and linked with each other by a system of hydrogen bonds. The magnetic susceptibility of compounds is determined by spins of Gd3+ ions that weakly antiferromagnetic coupled in dimeric cationic fragments. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：174 / 179
页数：6
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