Ir-catalysed formation of C-F bonds. From allylic alcohols to α-fluoroketones

被引：50
作者：
Ahlsten, Nanna [1 ]
Martin-Matute, Belen [1 ]
机构：
[1] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 29期
基金：
瑞典研究理事会;
关键词：
CARBONYL-COMPOUNDS; REDOX ISOMERIZATION; EFFICIENT SYNTHESIS; FLUORINATION; KETONES; RHODIUM; ALDOLS; COMPLEXES; ALDEHYDES; INSIGHT;
D O I：
10.1039/c1cc12653a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel iridium-catalysed tandem isomerisation/C-F bond formation from allylic alcohols and Selectfluor (R) to prepare alpha-fluorinated ketones as single constitutional isomers is reported.
引用
收藏
页码：8331 / 8333
页数：3
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