Ir-catalysed formation of C-F bonds. From allylic alcohols to α-fluoroketones

被引：49

作者：

Ahlsten, Nanna ^{[1
]}

Martin-Matute, Belen ^{[1
]}

机构：

[1] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 29期

基金：

瑞典研究理事会;

关键词：

CARBONYL-COMPOUNDS; REDOX ISOMERIZATION; EFFICIENT SYNTHESIS; FLUORINATION; KETONES; RHODIUM; ALDOLS; COMPLEXES; ALDEHYDES; INSIGHT;

D O I：

10.1039/c1cc12653a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel iridium-catalysed tandem isomerisation/C-F bond formation from allylic alcohols and Selectfluor (R) to prepare alpha-fluorinated ketones as single constitutional isomers is reported.

引用

页码：8331 / 8333

页数：3

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