Pressure-Induced Broadband Emission of 2D Organic-Inorganic Hybrid Perovskite (C6H5C2H4NH3)2PbBr4

被引:125
作者
Zhang, Long [1 ]
Wu, Lianwei [1 ]
Wang, Kai [1 ]
Zou, Bo [1 ]
机构
[1] Jilin Univ, State Key Lab Superhard Mat, Coll Phys, Changchun 130012, Jilin, Peoples R China
基金
美国国家科学基金会; 国家重点研发计划;
关键词
amorphization; band-gap narrowing; broadband emission; perovskites; pressure; WHITE-LIGHT EMISSION; OPTICAL-PROPERTIES; CRYSTAL-STRUCTURES; AMORPHIZATION; MECHANISM; SHIFT; BR;
D O I
10.1002/advs.201801628
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2D Ruddlesden-Popper halide perovskites, which incorporate hydrophobic organic interlayers to considerably improve environmental stability and optical properties diversity, have attracted substantial research attention for optoelectronic applications. The burgeoning broad emission arising from exciton self-trapping of 2D perovskites shows a strong dependence on a deformable structure. Here, the pressure-induced broadband emission of layered (001) Pb-Br perovskite with a large Stokes shift in the visible region is observed by finely improving lattice distortion to increase exciton-phonon coupling under hydrostatic pressure. Band gap narrows approximate to 0.5 eV under modest pressure, mainly due to the large compressibility of the orientational organic layer, confirming that the bulky organic cations notably influence the structure and, in turn, the various properties of materials. Sequential amorphization of the organic and inorganic layer is confirmed by high pressure Raman and X-ray diffraction measurements, suggesting the particularity of layered crystal structures. The mechanism constructed here offers a new route for tuning the optical properties of 2D perovskites.
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页数:6
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