Anion-induced AgI self-assemblies with electron deficient aromatic ligands: anion-π-system interactions as a driving force for templated coordination networks

被引:55
作者
Safin, Damir A. [1 ]
Pialat, Amelie [1 ]
Leitch, Alicea A. [1 ]
Tumanov, Nikolay A. [2 ]
Korobkov, Ilia [1 ]
Filinchuk, Yaroslav [2 ]
Brusso, Jaclyn L. [1 ]
Murugesu, Muralee [1 ]
机构
[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
[2] Catholic Univ Louvain, Inst Condensed Matter & Nanosci, B-1348 Louvain La Neuve, Belgium
基金
加拿大自然科学与工程研究理事会;
关键词
MASS-SPECTROMETRY; CRYSTAL-STRUCTURE; COMPLEXES; RECOGNITION; RINGS; 3,6-BIS(2-PYRIDYL)-1,2,4,5-TETRAZINE; SILVER(I);
D O I
10.1039/c5cc01597a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three novel 1D, 2D and 3D coordination polymers were successfully isolated using nitrogen based 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine (BPymTz) and 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligands with Ag-I ions. The formation of these supramolecular assemblies was templated through anion-pi-system interactions.
引用
收藏
页码:9547 / 9550
页数:4
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