Combination of mid-infrared spectroscopy and curve resolution method to follow the antioxidant action of alkylated diphenylamines

被引：11
作者：
Gracia, N. [1 ,2 ,3 ]
Thomas, S. [3 ]
Thibault-Starzyk, F. [3 ]
Lerasle, O. [2 ]
Duponchel, L. [1 ]
机构：
[1] USTL, LASIR, CNRS, UMR 8516, F-59655 Villeneuve Dascq, France
[2] TOTAL, Ctr Rech Solaize, F-69360 Solaize, France
[3] Univ Caen, ENSICAEN, Catalyse & Spectrochim Lab, CNRS, F-14050 Caen, France
来源：
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS | 2011年 / 106卷 / 02期
关键词：
Lubricants; Oxidation; Diphenylamine; FTIR; Chemometrics; MCR-ALS; ORTHOGONAL PROJECTION APPROACH; LIQUID-CHROMATOGRAPHY; INFRARED-SPECTROSCOPY; MULTIVARIATE; CHEMOMETRICS; INHIBITION; COMPONENTS;
D O I：
10.1016/j.chemolab.2010.08.017
中图分类号：
TP [自动化技术、计算机技术];
学科分类号：
0812 ;
摘要：
The inhibition of the oxidation of lubricating base oils by dinonyldiphenylamine has been studied by combined Fourier transform infrared (FTIR) spectroscopy and multivariate curve resolution-alternating least squares (MCR-ALS) method. This allowed to extract chemical information during the induction period. The substituted diphenylamines are progressively converted to a degraded form which can be followed with the chemometric analysis. When concentration of dinonyldiphenylamine is too low, the induction period ends and the oxidation of the base oils begins. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：210 / 215
页数：6
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