Inherently dinuclear iridium(iii) meso architectures accessed by cyclometalation of calix[4]arene-based bis(aryltriazoles)

被引：9

作者：

Bezzubov, Stanislav ^{[1
]}

Ermolov, Kirill ^{[2
]}

Gorbunov, Alexander ^{[2
]}

Kalle, Paulina ^{[1
]}

Lentin, Ivan ^{[2
]}

Latyshev, Gennadij ^{[2
]}

Kovalev, Vladimir ^{[2
]}

Vatsouro, Ivan ^{[2
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Lenins Hills 1, Moscow 119991, Russia

来源：

DALTON TRANSACTIONS | 2021年 / 50卷 / 45期

基金：

俄罗斯基础研究基金会;

关键词：

COMPLEXES BEARING; IR(III) COMPLEXES; LIGANDS; CYCLOADDITION; LUMINESCENCE; CALIXARENES; MONONUCLEAR; BINDING;

D O I：

10.1039/d1dt03579g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Conventional cyclometalation of calix[4]arene bis(aryltriazoles) with iridium(iii) chloride hydrate leads to unique meso architectures in which the Ir2Cl2 core is cross-bound by two (C<^>N)(2) ligands, which allows further replacement of the chloride bridges with ancillary ligands while maintaining the dinuclear structures of the complexes having independent or coupled iridium pairs.

引用

页码：16765 / 16769

页数：5

共 6 条

[1] Calix[4]arene-based bis[2]catenanes:: Synthesis and chiral resolution
Molokanova, Olena
Bogdan, Anca
Vysotsky, Myroslav O.
Bolte, Michael
Ikai, Tomoyuki
Okamoto, Yoshio
Boehmer, Volker
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (21) : 6157 - 6170
[2] Highly efficient phosphate diester transesterification by a calix[4]arene-based dinuclear zinc(II) catalyst
Molenveld, P
Kapsabelis, S
Engbersen, JFJ
Reinhoudt, DN
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (12) : 2948 - 2949
[3] Calix[4]arene-Based Bis(Nitric Oxide) Complexes: Synthesis, Physical Properties, and Structural Characterization
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[4] Coordination chemistry of a calix[4]arene-based NHC ligand: dinuclear complexes and comparison to IiPr2Me2
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[5] Tetrapyrazolyl-calix[4]arene-based supramolecular architectures from [Pd16L4] macrocycle to three-dimensional microporous channels
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[6] Novel calix[4]arene-based receptors with bis-squaramide moieties for colorimetric sensing of anions via two different interaction modes
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Zhang, Man
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