Reduction of carbon dioxide during the synthesis of metal nano-particles in water

被引：2

作者：

Rusonik, I

Polat, H

Cohen, H

Meyerstein, D

机构：

[1] Ben Gurion Univ Negev, Dept Chem, IL-84105 Beer Sheva, Israel

[2] Ismir Inst Technol, Dept Chem, Ulra Izmir, Turkey

[3] Nucl Res Ctr Negev, IL-84190 Beer Sheva, Israel

[4] Coll Judea & Samaria, Dept Biol Chem, Ariel, Israel

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 09期

关键词：

carbon dioxide; metal nano-particles; reduction; sodium borohydride;

D O I：

10.1016/S1387-7003(03)00247-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An effort was made to synthesize "carbon-free" metal (Fe-0, Co-0, Ni-0) nano-particles via the reduction of their salts with BH4- in aqueous solutions. Surprisingly it was found that when the synthesis is carried out in the presence of CO2, e.g., in aerated solutions, the CO2 is catalytically reduced by BH(4)(-)on the surface of the metal particles. Carbon-free metals can be prepared by reduction under an inert atmosphere. Thus metal surfaces might have acted as catalysts for CO2 fixation, probably via the initial formation of carbon clusters, in the reductive atmosphere in the prebiotic era. (C) 2003 Elsevier B.V. All rights reserved.

引用

收藏

页码：1266 / 1268

页数：3

相关论文

共 50 条

[21] Metal-Organic Frameworks for Electrocatalytic Reduction of Carbon Dioxide [J].

Kornienko, Nikolay ;

Zhao, Yingbo ;

Kiley, Christopher S. ;

Zhu, Chenhui ;

Kim, Dohyung ;

Lin, Song ;

Chang, Christopher J. ;

Yaghi, Omar M. ;

Yang, Peidong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (44) :14129-14135

[22] Copper/metal oxide heterostructures for electrochemical carbon dioxide reduction [J].

Yan, Jiang-Cheng ;

Wang, Fang-Mu ;

Yin, Shuai ;

Zhang, Jing ;

Jiang, Wei ;

Liu, Gui-Gao .

RARE METALS, 2025, :2239-2267

[23] Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction [J].

Kumar, Bijandra ;

Asadi, Mohammad ;

Pisasale, Davide ;

Sinha-Ray, Suman ;

Rosen, Brian A. ;

Haasch, Richard ;

Abiade, Jeremiah ;

Yarin, Alexander L. ;

Salehi-Khojin, Amin .

NATURE COMMUNICATIONS, 2013, 4

[24] Solvent-free synthesis of heterometallic metal-organic frameworks for the electrocatalytic reduction of carbon dioxide [J].

Irigaray, Maite Perfecto ;

Albo, Jonathan ;

Beobide, Garikoitz ;

Castillo, Oscar ;

Irabien, Angel ;

Perez-Yanez, Sonia .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2018, 74 :E281-E281

[25] Metal-based Heterogeneous Electrocatalysts for Electrochemical Reduction of Carbon Dioxide to Methane: Progress and Challenges [J].

Zheng, Yiqun ;

Wang, Yu ;

Yuan, Yuliang ;

Huang, Hongwen .

CHEMNANOMAT, 2021, 7 (05) :502-514

[26] Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers [J].

Shao, Ping ;

Yi, Luocai ;

Chen, Shumei ;

Zhou, Tianhua ;

Zhang, Jian .

JOURNAL OF ENERGY CHEMISTRY, 2020, 40 :156-170

[27] Photo-induced generation of dihydrogen and reduction of carbon dioxide using transition metal complexes [J].

Sutin, N ;

Creutz, C ;

Fujita, E .

COMMENTS ON INORGANIC CHEMISTRY, 1997, 19 (02) :67-92

[28] Metal-Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes [J].

Lieske, Lauren E. ;

Freeman, Lucas A. ;

Wang, Guocang ;

Dickie, Diane A. ;

Gilliard, Robert J., Jr. ;

Machan, Charles W. .

CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (24) :6098-6101

[29] Promoter Effects of Alkali Metal Cations on the Electrochemical Reduction of Carbon Dioxide [J].

Resasco, Joaquin ;

Chen, Leanne D. ;

Clark, Ezra ;

Tsai, Charlie ;

Hahn, Christopher ;

Jaramillo, Thomas F. ;

Chan, Karen ;

Bell, Alexis T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (32) :11277-11287

[30] Photocatalytic performance of metal poly(heptazine imide) for carbon dioxide reduction [J].

Yamaguchi, Aika ;

Miyazaki, Chihiro ;

Takezawa, Yunosuke ;

Seo, Goichiro ;

Saito, Yuki ;

Ohnuki, Ryosuke ;

Yoshioka, Shinya ;

Kanai, Kaname .

CARBON TRENDS, 2024, 16

← 1 2 3 4 5 →