Effect of Pb2+ on the photoluminescence characteristics of ZrO2: Mn2+ nanocrystals

被引:6
作者
Shu, FW
Feng, G
Meng, KL
Su, WL
Dong, X
Duo, RY
Yong, XQ
机构
[1] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
[2] Shandong Univ, Coll Mat Sci & Technol, Jinan 250100, Peoples R China
基金
中国国家自然科学基金;
关键词
ZrO4 : Mn; Pb; nanocrystal; photoluminescence; coprecipitation;
D O I
10.1016/S1387-7003(03)00249-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The photoluminescence (PL) properties of the Mn, Pb co-doped ZrO2 nanocrystals have been investigated in detail. A relatively broad and strong emission band centered at about 640 nm was observed originating from the T-4(1) ((4)G) to the (6)A(1), (S-6) transition of Mn-2divided by. In the presence of Pb-2divided by, the luminescent intensities of the ZrO2: Mn nanocrystals have been greatly enhanced due to the energy transfer from Pb-2divided by to Mn-2divided by. As a concentration quenching exists, the optimum value of Pb-2divided by is 5%. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:1275 / 1277
页数:3
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