Pt/Al2O3 and Pt/Ba-Al2O3 catalysts studied by temperature programmed desorption of oxygen:: Evidence for a low temperature desorbing species

被引:9
|
作者
Labalme, V [1 ]
Guilhaume, N [1 ]
Garbowski, E [1 ]
Primet, M [1 ]
机构
[1] Univ Lyon 1, CNRS, UMR 5634, LACE, F-69622 Villeurbanne, France
来源
关键词
platinum; alumina; oxygen; desorption;
D O I
10.1007/BF02475336
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
For fresh and aged Pt/Al2O3 catalysts, TPD of oxygen is fairly well related to the noble metal surface areas and to the catalytic activity in butane combustion, whereas for aged Pt/Ba-Al2O3 solids, the catalytic activity is still preserved despite a tremendous sintering of the metallic phase and seems to be connected to a surface barium superoxide.
引用
收藏
页码:207 / 214
页数:8
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