One-pot synthesis of polyfluoroterphenyls via palladium-catalyzed Suzuki-Miyaura coupling of chlorobromobenzene and C-H bond functionalization of perfluoroarenes

被引：8

作者：

Ma, Xiaowei ^{[1
]}

Gu, Ningning ^{[1
]}

Liu, Yan ^{[1
]}

Liu, Ping ^{[1
]}

Xie, Jianwei ^{[1
]}

Dai, Bin ^{[1
]}

Liu, Zhiyong ^{[1
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832003, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2015年 / 29卷 / 01期

基金：

中国国家自然科学基金;

关键词：

one pot; polyfluoroterphenyls; palladium catalysis; Suzuki-Miyaura; perfluoroarenes; TRANSITION-TEMPERATURES; DIRECT ARYLATION; HOST MATERIALS; EFFICIENT CATALYSTS; LIQUID-CRYSTALS; TERPHENYLS; COMPLEXES; POLYFLUOROARENES; INHIBITORS; STRATEGY;

D O I：

10.1002/aoc.3248

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

An efficient tandem route for the synthesis of polyfluoroterphenyl derivatives has been developed. The target compounds were obtained in moderate to good yields by a Pd(OAc)(2)-catalyzed three-component coupling reaction involving palladium-catalyzed direct CH activation of perfluoroarenes. This in turn will set the stage for a wide application of this useful reaction for the synthesis of fluorinated liquid crystal compounds containing the privileged polyfluoroterphenyl structure. Copyright (c) 2014 John Wiley & Sons, Ltd.

引用

页码：50 / 56

页数：7

共 55 条

[1] A practical and general synthesis of unsymmetrical terphenyls [J].