A hydrogen-bonded dichloromethane-perchlorate-water channel in the crystal structure of cis-[Ru(bpy)(2){PPh(o-tolyl)(2)}Cl+] [ClO4-]center dot CH2Cl2 center dot H2O

被引：9

作者：

Churchill, MR

Krajkowski, LM

Huynh, MHV

Takeuchi, KJ

机构：

[1] Department of Chemistry, Nat. Sci. and Mathematics Complex, State University of New York, Buffalo

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 1996年 / 26卷 / 01期

关键词：

ruthenium(II); bipyridyl; phenyldi(o-tolyl)phosphine; solvate; hydrogen bonding; crystal structure;

D O I：

10.1007/BF02018700

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The complex cis-[Ru(bpy)(2){PPh(o-tolyl)(2)}Cl+][ClO4-] crystallized from a solution in dichloromethane as the dichioromethane-water solvate. The structure was refined to R = 4.5% for those 2433 reflections with \F-o\ > 6 sigma(\F-o\). The octahedral Ru(II) cation is associated with metal-ligand distances as follows: Ru-Cl = 2.434(3)Angstrom, Ru-PPh(o-tol)(2) = 2.382(2)Angstrom, and Ru-N = 2.037(7) - 2.088(7)Angstrom. The structure is stabilized by a hydrogen-bonded CH2Cl2 ... ClO4-... H2O channel which incorporates adventitious water of crystallization.

引用

页码：67 / 73

页数：7

共 5 条

[1] CRYSTAL-STRUCTURE AND MOLECULAR-GEOMETRY OF DIMERIC AZULENEMANGANESE TRICARBONYL,[(C10H8)MN(CO)3]2 [J].