Chiral-Induced Spin Selectivity in Capacitively Coupled Molecules

被引:3
作者
Hedegard, Per [1 ]
机构
[1] Univ Copenhagen, Niels Bohr Inst, DK-2100 Copenhagen, Denmark
关键词
ELECTRON TRANSMISSION; MAGNETIZATION; MONOLAYERS; TRANSPORT; MAGNETISM;
D O I
10.1021/acs.jpca.2c01156
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The chiral-induced spin selectivity (CISS) effect is usually associated with electrons passing through chiral molecules. There are a number of experiments where external electrical fields rearrange electrons inside otherwise isolated molecules, allegedly also generating spin polarization of the molecule. There are theoretical suggestions of pairs of molecules generating spin polarizations in each other due to fluctuating electrical dipoles. This paper critically theoretically evaluates such spin-dependent charge reorganization (SDCR) effects. We find that such effects are not ruled out in principle, but they are very small and probably not detectable.
引用
收藏
页码:3157 / 3166
页数:10
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