Synthesis, characterization and liquid crystalline properties of novel benzimidazol-8-hydroxyquinoline complexes

The synthesis, characterization and liquid crystalline properties of N4, N4'-bis((1 H-benzo[d]imidazol-2-yl)methyl)-3,3'-dimethyl-[1,1'-biphenyl]-4,4'-diamine and of their corresponding Mn(II), Fe(II), Ni (II), Cu(II), and Zn(II) complexes are described. The ligand and complexes have been characterized by elemental analysis, magnetic susceptibility measurements (mu(eff)), conductometric measurements and Fourier Transform Infrared (FTIR), Nuclear Magnetic Resonance (H-1 NMR), (C-13-NMR) and UV-Vis spectroscopy. Spectral investigations suggested octahedral coordination geometrical arrangement for M(II) complexes. The phase transition temperatures were detected by differential scanning calorimetry (DSC) analysis and the phases are confirmed by optical polarizing microscopy (POM). The DSC and POM supported the mesomorphic properties of the uncoordinated ligand in which the enantiotropic smectic phases were recorded. However, not all of their corresponding M(II) complexes are liquid crystal. (C) 2017 Elsevier B.V. All rights reserved.