Sodium borohydride reduction of 4-aryl-N-trifluoroacetyl-3a,4,5,9b-tetrahydro-3H-cyclopenta[c]quinoline ozonide

被引：0

作者：

Tolstikov, Alexander G. ^{[1
]}

Savchenko, Rimma C. ^{[1
]}

Afon'kina, Svetlana R. ^{[1
]}

Lukina, Elena S. ^{[1
]}

Nedopekin, Denis V. ^{[1
]}

Khalilov, Leonard M. ^{[1
]}

Odinokov, Victor N. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, Ufa 450075, Russia

来源：

MENDELEEV COMMUNICATIONS | 2011年 / 21卷 / 05期

关键词：

OZONOLYSIS; HYDRIDE;

D O I：

10.1016/j.mencom.2011.09.019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of the title ozonide with 1 equiv. of sodium borohydride in ethanol leads to the transformation of the ozonide moiety into delta-lactone one, whereas the use of 5 equiv. of the reductant affords the corresponding 1,5-diol, with N-deacylation occurring in all cases.

引用

页码：285 / 286

页数：2

共 12 条

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