Aerobic oxidation of primary amines to oximes catalyzed by DPPH and WO3/Al2O3

被引：65

作者：

Suzuki, Ken ^{[1
]}

Watanabe, Tomonari ^{[1
]}

Murahashi, Shun-Ichi ^{[2
]}

机构：

[1] Asahi Kasei Chem Corp, Chem Technol Lab, Okayama 7118510, Japan

[2] Okayama Univ Sci, Dept Appl Chem, Okayama 7000005, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 11期

关键词：

amines; heterogeneous catalysis; oxidation; oximes; radical reactions;

D O I：

10.1002/anie.200705002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Catalytic teamwork: Aerobic oxidation of primary amines to the corresponding oximes proceeds highly efficiently in the presence of the catalysts 1,1-diphenyl-2-picrylhydrazyl (DPPH) and WO 3/Al2O3 under mild conditions (see scheme). This new method is both selective and environmentally benign. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2079 / 2081

页数：3

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